(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

Base Information

Chemical Name:(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)
CAS No.:1431223-31-2
Molecular Formula:C₃₂H₂₉FIN₃Pd
Molecular Weight:709.909
Hs Code.:

(Py<sub>3</sub>CH)Pd<sup>II</sup>(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

Synonyms:(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

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Chemical Property of (Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

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Technology Process of (Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

There total 7 articles about (Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 52409-22-0,51364-51-3
tris-(dibenzylideneacetone)dipalladium⁽⁰⁾

: 77429-58-4
tris(2-pyridyl)methane

: 1431224-04-2
2,6-dideutero-4-(tert-butyl)-5'-fluoro-2'-iodo-1,1'-biphenyl

: 1431223-31-2
(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

Guidance literature:: tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; 2,6-dideutero-4-(tert-butyl)-5'-fluoro-2'-iodo-1,1'-biphenyl; With 4-tert-butylpyridine; In tetrahydrofuran; at 50 ℃; Sealed tube;

tris(2-pyridyl)methane; In tetrahydrofuran;
DOI:10.1021/ja401557m

Reference yield:

: 109-06-8
α-picoline

: 1431223-31-2
(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere

1.2: 3.33 h / 0 - 65 °C / Inert atmosphere

2.1: 4-tert-butylpyridine / tetrahydrofuran / 50 °C / Sealed tube

With 4-tert-butylpyridine; n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1021/ja401557m

Reference yield:

: 372-48-5
2-fluoropyridine

: 1431223-31-2
(Py₃CH)Pd^II(4'-tert-butyl-2',6'-dideutero-5-fluoro-[1,1'-biphenyl]-2-yl)(I)

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere

1.2: 3.33 h / 0 - 65 °C / Inert atmosphere

2.1: 4-tert-butylpyridine / tetrahydrofuran / 50 °C / Sealed tube

With 4-tert-butylpyridine; n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1021/ja401557m