methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Base Information

Chemical Name:methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate
CAS No.:107222-32-2
Molecular Formula:C₂₈H₃₂O₂
Molecular Weight:400.561
Hs Code.:

Synonyms:methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

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Chemical Property of methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

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Technology Process of methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

There total 3 articles about methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.1%

: 107222-31-1
methyl 1,1a,1b,2,3,3a,4,5,5a,6,6a,6b,6c,6d,6e,6f-hexadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

: 107222-32-2
methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Guidance literature:: With dihydrogen peroxide; hydrazine; In tetrahydrofuran; ethanol; Ambient temperature;
DOI:10.1021/jo00383a017

Reference yield:

: 100-44-7
benzyl chloride

: 107222-32-2
methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Li, NH₃ / 1.) 1,2-dimethoxyethane, -78 deg C, 30 min, 2.) 1,2-dimethoxyethane, a) -78 deg C, 30 min, b) -33 deg C, 30 min

2: 2.) p-toluenosulfonic acid / 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h

3: 95.1 percent / H₂NNH₂, 30percent aq. H₂O₂ / tetrahydrofuran; ethanol / Ambient temperature

With ammonia; dihydrogen peroxide; lithium; toluene-4-sulfonic acid; hydrazine; In tetrahydrofuran; ethanol;
DOI:10.1021/jo00383a017

Reference yield:

: 107201-24-1
methyl octadecahydro-7-benzyl-3-oxo-1H-cyclopenta<3,4>pentaleno-<2,1,6-gha>pentaleno<1,2,3-cd>pentalene-7-carboxylate

: 107222-32-2
methyl octadecahydro-7-benzyl-1,6-methanocyclopenta<3,4>pentaleno<2,1,6-cde>pentaleno<2,1,6-gha>pentalene-7-carboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: 2.) p-toluenosulfonic acid / 1.) tert-butyl alcohol, benzene, irradiation, 23 h, 2.) benzene, reflux, 5 h

2: 95.1 percent / H₂NNH₂, 30percent aq. H₂O₂ / tetrahydrofuran; ethanol / Ambient temperature

With dihydrogen peroxide; toluene-4-sulfonic acid; hydrazine; In tetrahydrofuran; ethanol;
DOI:10.1021/jo00383a017