1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

Base Information

Chemical Name:1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol
CAS No.:866865-58-9
Molecular Formula:C₃₉H₆₀O₇Si
Molecular Weight:668.987
Hs Code.:

Synonyms:1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

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Chemical Property of 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

Chemical Property:

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Technology Process of 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

There total 9 articles about 1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 866865-56-7
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-deoxy-2-(formylmethyl)-4-O-methyl-3-O-myristoyl-D-glucitol

: 866865-58-9
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

Guidance literature:: With sodium chlorite; sodium dihydrogen phosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; for 1h;
DOI:10.1081/CAR-200068781

Reference yield:

: 866865-66-9
(1R,2S,3S,4R,5R)-4-Iodo-2-methoxy-6,8-dioxa-bicyclo[3.2.1]octan-3-ol

: 866865-58-9
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

Guidance literature:: Multi-step reaction with 8 steps

1.1: 110 mg / pyridine

2.1: 69 percent / 2,2'-dimethyl-2,2'-diazenediyldipropanenitrile / toluene / 3 h / 80 °C

3.1: 100 percent / water; methanol; triethylamine

4.1: 66 percent / tin(IV) chloride; triethylsilane / CH₂Cl₂ / 0.67 h / 20 °C

5.1: 97 percent / imidazole / dimethylformamide / 3 h / 20 °C

6.1: 95 percent / pyridine / 3 h / 20 °C

7.1: ozone / CH₂Cl₂ / -78 °C

7.2: 81 percent / triphenylphosphane / CH₂Cl₂ / 3 h / -78 - 20 °C

8.1: sodium chlorite; sodium dihydrogen phosphate; 2-methylbut-2-ene / 2-methyl-propan-2-ol; H₂O / 1 h

With pyridine; 1H-imidazole; methanol; triethylsilane; sodium chlorite; sodium dihydrogen phosphate; 2-methyl-but-2-ene; 2,2'-azobis(isobutyronitrile); water; tin(IV) chloride; ozone; triethylamine; In dichloromethane; water; N,N-dimethyl-formamide; toluene; tert-butyl alcohol;
DOI:10.1081/CAR-200068781

Reference yield:

: 866865-48-7
1,6-anhydro-2-deoxy-4-O-methyl-2-(prop-2-enyl)-β-D-glucopyranose

: 866865-58-9
1,5-anhydro-6-O-(tert-butyldiphenylsilyl)-2-(carboxymethyl)-2-deoxy-4-O-methyl-3-O-myristoyl-D-glucitol

Guidance literature:: Multi-step reaction with 5 steps

1.1: 66 percent / tin(IV) chloride; triethylsilane / CH₂Cl₂ / 0.67 h / 20 °C

2.1: 97 percent / imidazole / dimethylformamide / 3 h / 20 °C

3.1: 95 percent / pyridine / 3 h / 20 °C

4.1: ozone / CH₂Cl₂ / -78 °C

4.2: 81 percent / triphenylphosphane / CH₂Cl₂ / 3 h / -78 - 20 °C

5.1: sodium chlorite; sodium dihydrogen phosphate; 2-methylbut-2-ene / 2-methyl-propan-2-ol; H₂O / 1 h

With pyridine; 1H-imidazole; triethylsilane; sodium chlorite; sodium dihydrogen phosphate; 2-methyl-but-2-ene; tin(IV) chloride; ozone; In dichloromethane; water; N,N-dimethyl-formamide; tert-butyl alcohol;
DOI:10.1081/CAR-200068781