4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol

Base Information

• Chemical Name: 4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol
• CAS No.: 108233-89-2
• Molecular Formula: C₃₅H₄₆O₉
• Molecular Weight: 610.745
• Mol file: 108233-89-2.mol

Synonyms:4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol

Chemical Property of 4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol

There total 1 articles about 4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1S)-(-)-camphanic chloride (39637-74-6) + (+/-)-4-O-benzyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol (40773-58-8,40773-59-9,81601-24-3,92217-61-3,92217-62-4,99147-11-2,114716-74-4,116907-54-1,117708-44-8,124601-98-5,129707-20-6) → 4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol (108233-89-2) + 6-O-benzyl-1-O-camphanoyl-2,3:4,5-di-O-cyclohexylidene-myo-inositol (108340-80-3)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 25 ℃; for 1h;

DOI:10.1021/ja00245a059

Reference yield: 76.0%

4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol (108233-89-2) → C29H38O9 (108233-90-5,126722-38-1)

Guidance literature:

With acetyl chloride; In methanol; chloroform; at 23 ℃; for 1h;

DOI:10.1016/S0040-4020(01)89510-7

Reference yield:

4-O-benzyl-3-O-camphanoyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol (108233-89-2) → (L)-4-O-benzyl-2,3-O-cyclohexylidene-myo-inositol 1,4,5-(hexabenzyl)trisphosphate (116839-49-7)

Guidance literature:

Multi-step reaction with 3 steps

1: HCl (gas) / ethyl acetate; methanol / Ambient temperature

2: LiOH / 1,2-dimethoxy-ethane; H₂O / 25 °C

3: 1.) KH / 1.) THF, 60 deg C, 2.) THF, 25 deg C

With hydrogenchloride; lithium hydroxide; potassium hydride; In methanol; 1,2-dimethoxyethane; water; ethyl acetate;

DOI:10.1021/ja00245a059

upstream raw materials:

(1S)-(-)-camphanic chloride

(+/-)-4-O-benzyl-1,2:5,6-di-O-cyclohexylidene-myo-inositol

Downstream raw materials:

C₂₉H₃₈O₉

(L)-4-O-benzyl-2,3-O-cyclohexylidene-myo-inositol 1,4,5-(hexabenzyl)trisphosphate

(L)-4-O-benzyl-2,3-O-cyclohexylidene-myo-inositol