(R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Base Information

• Chemical Name: (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde
• CAS No.: 26462-78-2
• Molecular Formula: C₁₅H₂₄O₂
• Molecular Weight: 236.354
• Mol file: 26462-78-2.mol

Synonyms:(R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Chemical Property of (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde

There total 16 articles about (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2R)-2-[(1R)-4-methylcyclohex-3-en-1-yl]propan-1-ol (13835-75-1,18479-68-0,26462-81-7,26462-90-8,70518-81-9,70518-83-1,13835-30-8) → (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde (26462-78-2)

Guidance literature:

Multi-step reaction with 4 steps

1: Py

3: (i), (ii) aq. H₂SO₄

4: (i) O₂, hematoporphyrin, (UV-irradiation), (ii) KI, AcOH, (iii) Na₂Cr₂O₇, aq. H₂SO₄

With pyridine;

DOI:10.1021/ja00705a641

Reference yield:

(2R)-2-[(1R)-4-methylcyclohex-3-en-1-yl]propyl 3,5-dinitrobenzoate (13835-32-0) → (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde (26462-78-2)

Guidance literature:

Multi-step reaction with 5 steps

1: (hydrolysis)

2: Py

4: (i), (ii) aq. H₂SO₄

5: (i) O₂, hematoporphyrin, (UV-irradiation), (ii) KI, AcOH, (iii) Na₂Cr₂O₇, aq. H₂SO₄

With pyridine;

DOI:10.1021/ja00705a641

Reference yield:

(S)-2-Methyl-6-((R)-4-methyl-cyclohex-3-enyl)-heptan-4-one (26462-77-1) → (R)-4-((S)-1,5-Dimethyl-3-oxo-hexyl)-cyclohex-1-enecarbaldehyde (26462-78-2)

Guidance literature:

Multistep reaction; (i) O₂, hematoporphyrin, (UV-irradiation), (ii) KI, AcOH, (iii) Na₂Cr₂O₇, aq. H₂SO₄;

DOI:10.1021/ja00705a641

upstream raw materials:

4-[(R)-4-(5,5-Dimethyl-[1,3]dioxan-2-yl)-cyclohex-3-enyl]-2-isobutyl-2-methylsulfanyl-pentanoic acid

(S)-2-Methyl-6-((R)-4-methyl-cyclohex-3-enyl)-heptan-4-one

(1R)-5-[(1S)-3-Hydroxy-1,5-dimethylhexyl]-2-methylenecyclohexanol

D-limonene

Downstream raw materials:

Juvabion

(+)-epijuvabione

(+)-Epitodomatuic acid