2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone

Base Information

• Chemical Name: 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone
• CAS No.: 105801-92-1
• Molecular Formula: C₅₉H₉₀O₄
• Molecular Weight: 868.322
• Mol file: 105801-92-1.mol

Synonyms:2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone

Chemical Property of 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone

There total 9 articles about 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

C9H9(2)H3O4 (478703-13-8) + C50H80(2)H2O → 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone (105801-92-1)

Guidance literature:

C₉H₉⁽²⁾H₃O₄; With boric acid; In toluene; Heating;

C₅₀H₈₀⁽²⁾H₂O; With aluminum silicate; In hexane; benzene; at 40 - 45 ℃; for 6h;

With pyrographite; lead dioxide; acetic acid;

DOI:10.1002/jlcr.587

Reference yield:

3,4,5-trimethoxybenzoic acid methyl ester (1916-07-0) → 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone (105801-92-1)

Guidance literature:

Multi-step reaction with 6 steps

1.1: 87 percent / LiAlD₄ / diethyl ether / 4 h / Heating

2.1: PBr₃; pyridine / diethyl ether / 2 h / 0 - 5 °C

3.1: 74 percent / LiAlD₄ / diethyl ether / 4 h / Heating

4.1: 54 percent / 10 percent sulphuric acid; 40 percent acetic acid / acetic acid / 16 h / 25 - 30 °C

5.1: 64 percent / Na₂S₂O₄ / diethyl ether; H₂O

6.1: boric acid / toluene / Heating

6.2: silica alumina / benzene; hexane / 6 h / 40 - 45 °C

6.3: 60 percent / lead dioxide; charcoal carbon; acetic acid

With pyridine; sodium dithionite; lithium aluminium deuteride; sulfuric acid; boric acid; phosphorus tribromide; acetic acid; In diethyl ether; water; acetic acid; toluene;

DOI:10.1002/jlcr.587

Reference yield:

2,3-dimethoxy-5-[D3-methyl]-1,4-benzoquinone (131135-40-5) → 2-((all-E)-1,1-dideuterio-3,7,11,15,19,23,27,31,35,39-decamethyl-tetraconta-2,6,10,14,18,22,26,30,34,38-decaenyl)-5,6-dimethoxy-3-trideuteriomethyl-[1,4]benzoquinone (105801-92-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 64 percent / Na₂S₂O₄ / diethyl ether; H₂O

2.1: boric acid / toluene / Heating

2.2: silica alumina / benzene; hexane / 6 h / 40 - 45 °C

2.3: 60 percent / lead dioxide; charcoal carbon; acetic acid

With sodium dithionite; boric acid; In diethyl ether; water; toluene;

DOI:10.1002/jlcr.587

upstream raw materials:

C₉H₉⁽²⁾H₃O₄

3,4,5-trimethoxybenzoic acid methyl ester

2,3-dimethoxy-5-[D₃-methyl]-1,4-benzoquinone

Eudesmic acid