phenyl-bis(pyridyl-2-oxy)phosphane

Base Information

• Chemical Name: phenyl-bis(pyridyl-2-oxy)phosphane
• CAS No.: 86674-26-2
• Molecular Formula: C₁₆H₁₃N₂O₂P
• Molecular Weight: 296.265
• Mol file: 86674-26-2.mol

Synonyms:phenyl-bis(pyridyl-2-oxy)phosphane

Chemical Property of phenyl-bis(pyridyl-2-oxy)phosphane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of phenyl-bis(pyridyl-2-oxy)phosphane

There total 1 articles about phenyl-bis(pyridyl-2-oxy)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-hydroxypyridin (142-08-5) + Dichlorophenylphosphine (644-97-3) → phenyl-bis(pyridyl-2-oxy)phosphane (86674-26-2)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.poly.2016.08.041

Reference yield: 60.0%

fac-tris(methylisonitrile)tricarbonylmolybdenum (17549-17-6,79516-89-5) + phenyl-bis(pyridyl-2-oxy)phosphane (86674-26-2) → tricarbonyl[phenyl-bis(pyridyl-2-oxy)phosphane]molybdenum*0.5THF

Guidance literature:

In tetrahydrofuran; under purified N2 or Ar, exclusion of moisture and air; a soln. of equiv. amts. of the metal compd. and the phosphane in THF is heated to boiling under reflux; filtn., removal of solvent in vac., washing with THF, recrystn. from THF; elem. anal.;

Reference yield: 56.0%

N-trans-[Ru(2-pyridyloxy)2(norbornadiene)] + phenyl-bis(pyridyl-2-oxy)phosphane (86674-26-2) → [PhP(μ-2-pyridyloxy)3Ru(κ-2-pyridyloxy)]

Guidance literature:

In acetonitrile; for 3h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1002/ejic.201701386

upstream raw materials:

2-hydroxypyridin

Dichlorophenylphosphine

Downstream raw materials:

tricarbonyl[phenyl-bis(pyridyl-2-oxy)phosphane]chromium