5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

Base Information

Chemical Name:5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride
CAS No.:86568-90-3
Molecular Formula:C₃₆H₃₇N₃O₄*ClH
Molecular Weight:612.168
Hs Code.:

Synonyms:5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

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Chemical Property of 5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

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Technology Process of 5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

There total 12 articles about 5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 59435-08-4
benzyl 5-formyl-3,4-dimethylpyrrole-2-carboxylate

: 86568-89-0
5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-2,2'-dipyrromethane

: 86568-90-3
5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

Guidance literature:: With hydrogenchloride; In dichloromethane; Ambient temperature; 1.) 30 s, 2.) 10 min;
DOI:10.1021/ja00359a012

Reference yield:

: 86568-84-5
5-benzyloxycarbonyl-3,4-dimethylpyrrole-2-carboxylic acid

: 86568-90-3
5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

Guidance literature:: Multi-step reaction with 8 steps

1: thionyl chloride / benzene / 1.) 40 deg C, 1 h, 2.) room temperature

2: 68 percent / N,N-dimethylaniline / 1.) 70 deg C, 1 h, 2.) room temperature, 44 h

3: 98 percent / triethylamine, hydrogen / palladium on charcoal / tetrahydrofuran / 3 h / Ambient temperature

4: 96 percent / sodium bicarbonate, potassium iodide, iodine / H₂O; methanol / 4 h / 60 °C

5: 94 percent / sodium acetate, hydrogen / Adams catalyst / methanol / 2 h / Ambient temperature

6: 84 percent / sodium acetate / acetic acid / 1.5 h / 150 °C

7: 85 percent / trifluoroacetic acid / 1.5 h

8: 86 percent / 1.) gaseous hydrogen chloride / CH₂Cl₂ / Ambient temperature; 1.) 30 s, 2.) 10 min

With hydrogenchloride; thionyl chloride; hydrogen; iodine; sodium acetate; sodium hydrogencarbonate; N,N-dimethyl-aniline; triethylamine; trifluoroacetic acid; potassium iodide; platinum(IV) oxide; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane; water; acetic acid; benzene;
DOI:10.1021/ja00359a012

Reference yield:

: 86568-87-8
2-((tert-butyloxy)carbonyl)-5-iodo-3,4-dimethylpyrrole

: 86568-90-3
5-((benzyloxy)carbonyl)-3,3',4,4'-tetramethyl-5'-(5-((benzyloxy)carbonyl)-3,4-dimethylpyrrol-2-yl)-2,2'-dipyrromethene hydrochloride

Guidance literature:: Multi-step reaction with 4 steps

1: 94 percent / sodium acetate, hydrogen / Adams catalyst / methanol / 2 h / Ambient temperature

2: 84 percent / sodium acetate / acetic acid / 1.5 h / 150 °C

3: 85 percent / trifluoroacetic acid / 1.5 h

4: 86 percent / 1.) gaseous hydrogen chloride / CH₂Cl₂ / Ambient temperature; 1.) 30 s, 2.) 10 min

With hydrogenchloride; hydrogen; sodium acetate; trifluoroacetic acid; platinum(IV) oxide; In methanol; dichloromethane; acetic acid;
DOI:10.1021/ja00359a012