C₅₂H₅₀N₂O₇Si₂

Base Information

• Chemical Name: C₅₂H₅₀N₂O₇Si₂
• CAS No.: 1352916-64-3
• Molecular Formula: C₅₂H₅₀N₂O₇Si₂
• Molecular Weight: 871.149
• Mol file: 1352916-64-3.mol

Synonyms:C₅₂H₅₀N₂O₇Si₂

Chemical Property of C₅₂H₅₀N₂O₇Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₂H₅₀N₂O₇Si₂

There total 17 articles about C₅₂H₅₀N₂O₇Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

C50H48N2O6Si2 (1352916-67-6) + acetic anhydride (108-24-7) → C52H50N2O7Si2 (1352916-64-3)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/anie.201104504

Reference yield:

C53H54N2O9SSi2 → C52H50N2O7Si2 (1352916-64-3)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.201104504

Reference yield:

C28H38O8Si (1352916-42-7) → C52H50N2O7Si2 (1352916-64-3)

Guidance literature:

Multi-step reaction with 11 steps

1.1: pyridine / 5.5 h / 20 °C / Inert atmosphere

2.1: lithium triethylborohydride / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

3.1: dmap / dichloromethane / 5 h / 20 °C / Inert atmosphere

4.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 15 h / 0 °C / Inert atmosphere

5.1: pyridine; Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

6.1: sodium chlorite; disodium hydrogenphosphate; 2-methyl-but-2-ene / water; tert-butyl alcohol / 2 h / 0 °C / Inert atmosphere

7.1: trifluoroacetic anhydride / nitromethane / 2.5 h / 80 °C / Inert atmosphere; Molecular sieve

7.2: 2 h / 20 °C / Inert atmosphere

8.1: 1H-imidazole; dmap / dichloromethane / 20 h / 20 °C / Inert atmosphere

9.1: trifluoroacetic acid / water; isopropyl alcohol / 62 h / 20 °C / Inert atmosphere

10.1: ammonium cerium (IV) nitrate / acetonitrile / 1 h / 0 °C / pH 7 / Inert atmosphere; aq. buffer

11.1: triethylamine / dichloromethane / 1 h / 20 °C / Inert atmosphere

With pyridine; 1H-imidazole; dmap; sodium chlorite; disodium hydrogenphosphate; ammonium cerium (IV) nitrate; 2-methyl-but-2-ene; lithium triethylborohydride; Dess-Martin periodane; pyridine hydrogenfluoride; triethylamine; trifluoroacetic acid; trifluoroacetic anhydride; In tetrahydrofuran; nitromethane; dichloromethane; water; isopropyl alcohol; acetonitrile; tert-butyl alcohol; 7.1: Friedel Crafts acylation;

DOI:10.1002/anie.201104504

upstream raw materials:

C₂₈H₃₈O₈Si

C₃₀H₄₀O₉Si

C₃₀H₄₂O₉Si

C₃₅H₅₀O₁₁Si

Downstream raw materials:

FL-120B'