{2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

Base Information

Chemical Name:{2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]
CAS No.:1026786-15-1
Molecular Formula:C₄₄H₆₄N₂Ni₂O₂P₂
Molecular Weight:832.332
Hs Code.:

Synonyms:{2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

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Chemical Property of {2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

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Technology Process of {2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

There total 8 articles about {2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: trans-chloro(methyl)bis(trimethylphosphane)nickel(II)

: sodium 2,7-di[(2,6-diisopropylphenyl)iminomethyl]-1,8-naphthalenediolate

: 1026786-15-1
{2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

Guidance literature:: In diethyl ether; benzene; at 20 ℃; for 1h;

Reference yield:

: {methyl(chloro)(trimethylphosphine)2}nickel(II)

: 2,7-di(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene

: 1026786-15-1
trans-[Ni(trimethylphosphine)(methyl)]2(2,7-di(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-2H))

Guidance literature:: With sodium hydride; In tetrahydrofuran; treatment with NaH and then addn. of NiCl(Me)(PMe3)2;
DOI:10.1021/om800208f

Reference yield:

: 83-31-8
1,8-naphthosultone

: 1026786-15-1
{2,7-di-[(2,6-diisopropylphenyl)imino]-1,8-naphthalenediolato}bis[(methyl)-(trimethylphosphine)Ni(II)]

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium hydroxide / 1 h / 260 °C

1.2: 0.5 h / 100 °C

2.1: sodium hydride / diethyl ether; N,N-dimethyl-formamide / 0 °C

2.2: 6 h / 0 - 20 °C

3.1: n-butyllithium; N,N,N,N,-tetramethylethylenediamine / diethyl ether / 8 h / 0 °C

3.2: 0 - 20 °C

4.1: hydrogenchloride / dichloromethane; isopropyl alcohol / 4 h / 0 - 20 °C

5.1: formic acid / dichloromethane / 6 h / Reflux; Molecular sieve

6.1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / 20 °C

7.1: diethyl ether; benzene / 1 h / 20 °C

With hydrogenchloride; n-butyllithium; formic acid; N,N,N,N,-tetramethylethylenediamine; sodium hydride; potassium hydroxide; In tetrahydrofuran; diethyl ether; dichloromethane; N,N-dimethyl-formamide; isopropyl alcohol; mineral oil; benzene;