Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

Base Information

Chemical Name:Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester
CAS No.:138124-12-6
Molecular Formula:C₁₈H₂₄O₄
Molecular Weight:304.386
Hs Code.:

Synonyms:Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

Suppliers and Price of Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

Chemical Property:

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Technology Process of Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

There total 6 articles about Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

: 79026-61-2
(R)-3-benzyloxy-2-methylpropanal

: 171011-57-7
Acetic acid 2-tributylstannanyl-penta-2,3-dienyl ester

: 138124-12-6
Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

: 138124-13-7
(2R,3R,4S)-(+)-1-(benzyloxy)-2,4-dimethyl-7-acetoxy-5-heptyn-3-ol

: 137920-27-5
(2R,3S,4R)-(+)-1-(benzyloxy)-2,4-dimethyl-7-acetoxy-5-heptyn-3-ol

Guidance literature:: boron trifluoride diethyl etherate; In dichloromethane; at -78 ℃; for 4h; Yields of byproduct given;
DOI:10.1021/jo00030a036

Reference yield:

: 79026-61-2
(R)-3-benzyloxy-2-methylpropanal

: 171011-57-7
Acetic acid 2-tributylstannanyl-penta-2,3-dienyl ester

: 138124-12-6
Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

: 170899-15-7
Acetic acid (4S,5S,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

Guidance literature:: With indium(III) chloride; In ethyl acetate; Yield given. Yields of byproduct given. Title compound not separated from byproducts; 1.) -78 deg C to room temperature, 2.) room temperature, 20 h;
DOI:10.1021/jo970650u

Reference yield:

: 79026-61-2
(R)-3-benzyloxy-2-methylpropanal

: 171011-57-7
Acetic acid 2-tributylstannanyl-penta-2,3-dienyl ester

: 138124-12-6
Acetic acid (4R,5R,6R)-7-benzyloxy-5-hydroxy-4,6-dimethyl-hept-2-ynyl ester

Guidance literature:: With Trichlorbutylstannan; Yield given. Multistep reaction; 1.) CH₂Cl₂, 0 deg C, 2.) CH₂Cl₂, -78 deg C;
DOI:10.1021/jo970650u