tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate

Base Information

• Chemical Name: tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate
• CAS No.: 78937-17-4
• Molecular Formula: C₂₃H₁₅O₅PV*C₂₄H₂₀P
• Molecular Weight: 792.681
• Mol file: 78937-17-4.mol

Synonyms:tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate

Chemical Property of tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate

Chemical Property:

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Technology Process of tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate

There total 1 articles about tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

3Na(1+)*V(CO)5(3-)=Na3V(CO)5 + tetraphenylphosphonium bromide (2751-90-8) → tetraphenylphosphonium (triphenylphosphine)pentacarbonylvanadate (78937-17-4)

Guidance literature:

In ammonia; under N2 or Ar2, addn. of Ph4PBr to Na3V(CO)5 soln. at -78°C; evapn. of NH3, dissolving of residue in THF, filtration, concn., addn. of diethyl ether, recrystn. from acetone; elem. anal.;

DOI:10.1021/ja00410a019

upstream raw materials:

tetraphenylphosphonium bromide