(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

Base Information

Chemical Name:(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine
CAS No.:203452-32-8
Molecular Formula:C₁₉H₁₉NO₂S
Molecular Weight:325.431
Hs Code.:

Synonyms:(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

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Technology Process of (2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

There total 1 articles about (2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: (S)-2-Benzyl-1,4-bis-(toluene-4-sulfonyl)-1,2,3,4-tetrahydro-pyridine

: 203452-32-8
(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

Guidance literature:: With tin(IV) chloride; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1055/s-1998-1567

Reference yield: 97.0%

: 203452-32-8
(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

: 203452-34-0
(1S,6R)-3-tosyl-1,2,3,4,5,6-hexahydro-2,6-methano[3]benzazocine

Guidance literature:: With triethylsilane; trifluoroacetic acid; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1055/s-1998-1567

Reference yield:

: 203452-32-8
(2R,6R)-3-(Toluene-4-sulfonyl)-1,2,3,6-tetrahydro-2,6-methano-benzo[d]azocine

: 18715-91-8,64043-31-8
(2R,6S)-1,2,3,4,5,6-Hexahydro-2,6-methano-benzo[d]azocine

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / Et₃SiH, CF₃COOH / CH₂Cl₂ / 1 h / Ambient temperature

2: 6percent Na(Hg) / tetrahydrofuran; methanol / 12 h / Heating

With triethylsilane; sodium amalgam; trifluoroacetic acid; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1055/s-1998-1567