n-Bu₃GeGePh₃

Base Information

• Chemical Name: n-Bu₃GeGePh₃
• CAS No.: 37965-69-8
• Molecular Formula: C₃₀H₄₂Ge₂
• Molecular Weight: 547.843
• Mol file: 37965-69-8.mol

Synonyms:n-Bu₃GeGePh₃

Chemical Property of n-Bu₃GeGePh₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of n-Bu₃GeGePh₃

There total 3 articles about n-Bu₃GeGePh₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

Bu3GeCH2CN (894804-47-8) + triphenylgermane (2816-43-5) → n-Bu3GeGePh3 (37965-69-8)

Guidance literature:

In acetonitrile; High Pressure; under N2 atm. to soln. Bu3GeCH2CN in MeCN soln. Ph3GeH in MeCN was addedand heated in tube sealed with Teflon plug at 90°C for 50 min; volatiles were removed in vacuo; identified by NMR;

DOI:10.1021/om060115x

Reference yield: 83.0%

triphenylgermane (2816-43-5) + (dimethylamino)tributylgermane (681-86-7) → n-Bu3GeGePh3 (37965-69-8)

Guidance literature:

In acetonitrile; byproducts: HNMe2; under N2 atm. to soln. Bu3GeNMe2 in MeCN soln. Ph3GeH in MeCN was added and refluxed for 48 h; soln. was allowed to cool, volatiles were removed in vacuo, Kugelrohr distn. (180°C, 0.10 Torr); elem. anal.;

DOI:10.1021/om060115x

Reference yield:

tri-n-butylchlorogermane (2117-36-4) → n-Bu3GeGePh3 (37965-69-8)

Guidance literature:

Multi-step reaction with 2 steps

1: diisopropylamine; n-BuLi / hexane; tetrahydrofuran

2: acetonitrile

With diisopropylamine; n-BuLi; In tetrahydrofuran; hexane; acetonitrile;

DOI:10.1021/om060115x

upstream raw materials:

Bu₃GeCH₂CN

triphenylgermane

(dimethylamino)tributylgermane

tri-n-butylchlorogermane

Downstream raw materials:

triphenylgermane

hexaphenyldigermane

tributylgermanium hydride

Hexabutyl-digermanium