benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol

Base Information

• Chemical Name: benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol
• CAS No.: 128266-14-8
• Molecular Formula: C₂₅H₃₈O₂
• Molecular Weight: 370.576
• Mol file: 128266-14-8.mol

Synonyms:benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol

Chemical Property of benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol

There total 6 articles about benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

benzyl ether of 10,14-dimethyl-6-formylpentadeca-5E,9Z,13-trien-1-ol → benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol (128266-14-8)

Guidance literature:

With sodium tetrahydroborate; In ethanol; at 20 ℃; for 1.5h;

DOI:10.1007/BF00963009

Reference yield:

(cis-3,7-Dimethyl-2,6-octadienyl) phenyl sulfide (31162-76-2,35162-74-4,35162-79-9) → benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol (128266-14-8)

Guidance literature:

Multi-step reaction with 6 steps

1: 1) BuLi / 1) THF, hexane, 3.5 h, 2) 1.5 h

2: 89 percent / Li, NH₃ / diethyl ether / 4 h / -40 °C

3: 68 percent / H₂SO₄ / acetone; H₂O / 4 h / Heating

4: diethyl ether / 1.5 h / 20 °C

6: 90 percent / NaBH₄ / ethanol / 1.5 h / 20 °C

With sodium tetrahydroborate; n-butyllithium; sulfuric acid; ammonia; lithium; In diethyl ether; ethanol; water; acetone;

DOI:10.1007/BF00963009

Reference yield:

6,10-dimethylundeca-5Z,9-dien-1-al (125556-28-7) → benzyl ether of 10,14-dimethyl-6-hydroxymethylpentadeca-5E,9Z,13-trien-1-ol (128266-14-8)

Guidance literature:

Multi-step reaction with 3 steps

1: diethyl ether / 1.5 h / 20 °C

3: 90 percent / NaBH₄ / ethanol / 1.5 h / 20 °C

With sodium tetrahydroborate; In diethyl ether; ethanol;

DOI:10.1007/BF00963009

upstream raw materials:

(cis-3,7-Dimethyl-2,6-octadienyl) phenyl sulfide

6,10-dimethylundeca-5Z,9-dien-1-al

6,10-dimethylundeca-5Z,9-dien-1-al tert-butylimine

(Z)-6,10-Dimethyl-5,9-undecadienal ethylene acetal