dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

Base Information

Chemical Name:dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)
CAS No.:86747-89-9
Molecular Formula:C₄₂H₇₅O₃P₃Rh₂
Molecular Weight:926.788
Hs Code.:

Synonyms:dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

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Chemical Property of dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

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Technology Process of dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

There total 1 articles about dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 71380-76-2
cis-dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III)

: 501-65-5
diphenyl acetylene

: 103-30-0
(E)-1,2-diphenyl-ethene

: 86747-89-9
dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

: 6476-36-4
tris(1-methylethyl)phosphine

Guidance literature:: In toluene; byproducts: CO2; to Rh complex in toluene added diphenylacetylene (molar ratio 1:3) at room temp. for 3 h; washed with hexane, recrystd. from toluene/hexane, elem. anal.;
DOI:10.1021/ja00358a015

Reference yield: 15.0%

: 86747-89-9
dihydrido(carbonato)(diphenylacetylene)tris(triisopropylphosphine)rhodium(III)

: 71380-76-2
cis-dihydrido(bicarbonato)bis(triisopropylphosphine)rhodium(III)

: 74521-39-4
Rh₂(CO)3(P(C₃H₇)3)3

: 378784-00-0,7440-16-6
rhodium

: 103-29-7
1,1'-(1,2-ethanediyl)bisbenzene

Guidance literature:: With H₂; In toluene; under N2, Rh complex in toluene stirred under H2 at room temp. for 12 h; filtered, concd., dissolved in hexane, cooled to -70°C;
DOI:10.1021/ja00358a015