1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE

Base Information

• Chemical Name: 1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE
• CAS No.: 818-15-5
• Molecular Formula: C₁₈H₃₂O₄
• Molecular Weight: 312.45
• Mol file: 818-15-5.mol

Synonyms:1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE

Chemical Property of 1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE

Chemical Property:

• PSA: 70.50000
• LogP: 1.74210

Purity/Quality:

99% ^*data from raw suppliers

Benzo[d][1,3]dioxole-5,6-diamine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE

There total 3 articles about 1,2-DIAMINO-4,5-METHYLENE-DIOXYBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

12-Hydroxy-6-oxo-heptadec-10-insaeure-methylester (818-17-7) → 6,12-Dihydroxy-heptadec-10-insaeure-methylester (818-15-5)

Guidance literature:

With sodium tetrahydroborate;

DOI:10.1021/jm00325a010

Reference yield:

7-Acetoxy-dodec-5-insaeure-chlorid → 6,12-Dihydroxy-heptadec-10-insaeure-methylester (818-15-5)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) Et₃N, (ii) aq. KOH, (iii) /BRN= 102415/

2: NaBH₄

With sodium tetrahydroborate;

DOI:10.1021/jm00325a010

Reference yield:

7-Acetoxy-dodec-5-ynoic acid → 6,12-Dihydroxy-heptadec-10-insaeure-methylester (818-15-5)

Guidance literature:

Multi-step reaction with 3 steps

1: (COCl)2

2: (i) Et₃N, (ii) aq. KOH, (iii) /BRN= 102415/

3: NaBH₄

With sodium tetrahydroborate; oxalyl dichloride;

DOI:10.1021/jm00325a010

upstream raw materials:

12-Hydroxy-6-oxo-heptadec-10-insaeure-methylester

Refernces