Technology Process of C39H57NO3SSi
There total 12 articles about C39H57NO3SSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
isopropyltriphenylphosphonium iodide;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at 0 ℃;
for 0.166667h;
C36H51NO4SSi;
In
tetrahydrofuran; hexane;
for 0.25h;
Further stages.;
DOI:10.1021/ol070381m
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 95 percent / propionic acid / 32 h / Heating
2.1: 93 percent / DIBAL / CH2Cl2; toluene / 0.25 h / -78 °C
3.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / 0 °C
3.2: 84 percent / tetrahydrofuran; hexane / 0.25 h
With
n-butyllithium; diisobutylaluminium hydride; propionic acid;
In
tetrahydrofuran; hexane; dichloromethane; toluene;
1.1: Johnson-Claisen rearrangement / 3.2: Wittig reaction;
DOI:10.1021/ol070381m
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 883 mg / sulfuric acid / tetrahydrofuran / 1 h
2.1: 91 percent / tetrahydrofuran / 0.75 h / -78 °C
3.1: 95 percent / propionic acid / 32 h / Heating
4.1: 93 percent / DIBAL / CH2Cl2; toluene / 0.25 h / -78 °C
5.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / 0 °C
5.2: 84 percent / tetrahydrofuran; hexane / 0.25 h
With
n-butyllithium; sulfuric acid; diisobutylaluminium hydride; propionic acid;
In
tetrahydrofuran; hexane; dichloromethane; toluene;
3.1: Johnson-Claisen rearrangement / 5.2: Wittig reaction;
DOI:10.1021/ol070381m
