2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Base Information

Chemical Name:2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate
CAS No.:945550-04-9
Molecular Formula:C₂₉H₂₃Cl₃FNO₈
Molecular Weight:638.861
Hs Code.:

Synonyms:2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Suppliers and Price of 2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

There total 6 articles about 2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 945550-42-5
2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranoside

: 545-06-2
trichloroacetonitrile

: 945550-04-9
2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃;
DOI:10.1039/b702961f

Reference yield:

: allyl 6-O-triphenylmethyl-2,3,4-tri-O-benzoyl-α-D-mannopyranoside

: 945550-04-9
2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / acetic acid; H₂O / 3 h / 70 °C

2: 53 percent / DAST / CH₂Cl₂ / 1.5 h / -40 - 20 °C

3: 89 percent / PdCl₂ / methanol / 4 h / 40 °C

4: 80 percent / DBU / CH₂Cl₂ / 20 °C

With 1,8-diazabicyclo[5.4.0]undec-7-ene; 4,4'-diaminostilbene-2,2'-disulfonic acid; palladium dichloride; In methanol; dichloromethane; water; acetic acid;
DOI:10.1039/b702961f

Reference yield:

: 945550-41-4
allyl 2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranoside

: 945550-04-9
2,3,4-tri-O-benzoyl-6-deoxy-6-fluoro-α-D-mannopyranosyl trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / PdCl₂ / methanol / 4 h / 40 °C

2: 80 percent / DBU / CH₂Cl₂ / 20 °C

With 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium dichloride; In methanol; dichloromethane;
DOI:10.1039/b702961f