trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Base Information

Chemical Name:trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine
CAS No.:1151538-56-5
Molecular Formula:C₂₆H₂₉NO₂S₂
Molecular Weight:451.654
Hs Code.:

Synonyms:trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

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Technology Process of trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

There total 1 articles about trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 883458-47-7
(R)-(-)-N-pentylidene-p-toluenesulfinamide

: 1029690-05-8
(S)-2-(p-toluenesulfinyl)benzyl iodide

: 1151538-56-5
trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1151538-48-5
cis-(2R,3S)-2-butyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1252974-73-4
cis-(2S,3R)-2-butyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

Guidance literature:: With sodium hexamethyldisilazane; In tetrahydrofuran; at -78 ℃; for 0.0166667h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/chem.201000217

Reference yield: 70.0%

: 1151538-56-5
trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine

: 1151538-61-2
trans-(2S,3S)-2-butyl-3-phenylaziridine

Guidance literature:: trans-(2S,3S)-2-butyll-3-[(S)-2-(p-toluenesulfinyl)phenyl]-1-[(R)-(p-toluenesulfinyl)]aziridine; With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.25h; Inert atmosphere;

With ammonium chloride; In tetrahydrofuran; hexane; water; Inert atmosphere;
DOI:10.1021/jo900381b