O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide

Base Information

• Chemical Name: O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide
• CAS No.: 161315-64-6
• Molecular Formula: C₆₉H₆₅N₅O₁₇
• Molecular Weight: 1236.3
• Mol file: 161315-64-6.mol

Synonyms:O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide

Chemical Property of O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide

There total 4 articles about O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-mannopyranosyl)-(1*4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1*4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-β-D-glucopyranosyl azide → O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide (161315-64-6)

Guidance literature:

With methanol; sodium methylate; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1021/ja029346v

Reference yield: 92.0%

C72H66F3N5O20S (185797-99-3) → O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide (161315-64-6)

Guidance literature:

C₇₂H₆₆F₃N₅O₂₀S; With water; In N,N-dimethyl-formamide; at 50 ℃; for 24h; Inert atmosphere;

With sodium methylate; In methanol; at 20 ℃; for 1h; Inert atmosphere;

With ion-exchange resin; In methanol; Inert atmosphere;

DOI:10.1021/jo900016j

Reference yield: 65.0%

C105H101N5O22S → O-(4,6-O-benzylidene-β-D-mannopyranosyl)-(1->4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl azide (161315-64-6) + O-(3,4,6-tri-O-benzyl-2-deoxy-2-thiobenzyl-α-D-mannopyranosyl)-(1*3)-O-(2-O-acetyl-β-D-mannopyranosyl)-(1*4)-O-(3,6-di-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1*4)-3,6-di-O-benzyl-2-deoxy-2-phthalimido-1-β-D-glucopyranosyl azide

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 0 ℃; for 0.333333h;

DOI:10.1021/ja029346v

upstream raw materials:

C₇₀H₆₃N₅O₁₈

C₇₂H₆₆F₃N₅O₂₀S