(1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin

Base Information

• Chemical Name: (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin
• CAS No.: 87883-42-9
• Molecular Formula: C₅₆H₆₇Cl₃N₄O₄
• Molecular Weight: 966.531
• Mol file: 87883-42-9.mol

Synonyms:(1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin

Chemical Property of (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin

There total 10 articles about (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

C41H51Cl3N2O8 (87883-41-8) + 4,4'-diethyl-3,3'-dimethyl-2,2'-dipyrrylmethane-5,5'-dicarbaldehyde (4758-81-0) → (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin (87883-42-9)

Guidance literature:

DOI:10.1021/ja00364a065

Reference yield:

2',5'-dimethoxycinnamaldehyde (33538-93-1) → (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin (87883-42-9)

Guidance literature:

Multi-step reaction with 9 steps

2: H₂ / Pd/C

3: 74 percent / TiCl₄ / CH₂Cl₂ / Ambient temperature

5: H₂ / Pd/C

6: acid

7: 85 percent / p-TsOH

8: H₂ / 10percent Pd/C

9: 24 percent

With hydrogen; titanium tetrachloride; toluene-4-sulfonic acid; palladium on activated charcoal; In dichloromethane;

DOI:10.1021/ja00364a065

Reference yield:

1,2,4-Trichloro-5-[(1E,3E)-4-(2,5-dimethoxy-phenyl)-buta-1,3-dienyl]-3,6-dimethoxy-benzene (87883-36-1) → (1Z,4Z,9Z,15Z)-5-(4-{2,5-Dimethoxy-4-[4-(2,4,5-trichloro-3,6-dimethoxy-phenyl)-butyl]-phenyl}-butyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin (87883-42-9)

Guidance literature:

Multi-step reaction with 8 steps

1: H₂ / Pd/C

2: 74 percent / TiCl₄ / CH₂Cl₂ / Ambient temperature

4: H₂ / Pd/C

5: acid

6: 85 percent / p-TsOH

7: H₂ / 10percent Pd/C

8: 24 percent

With hydrogen; titanium tetrachloride; toluene-4-sulfonic acid; palladium on activated charcoal; In dichloromethane;

DOI:10.1021/ja00364a065

upstream raw materials:

C₄₁H₅₁Cl₃N₂O₈

4,4'-diethyl-3,3'-dimethyl-2,2'-dipyrrylmethane-5,5'-dicarbaldehyde

2',5'-dimethoxycinnamaldehyde

1,2,4-Trichloro-5-[4-(2,5-dimethoxy-phenyl)-butyl]-3,6-dimethoxy-benzene

Downstream raw materials:

2,3,5-Trichloro-6-(4-{3,6-dioxo-4-[4-((1Z,4Z,9Z,15Z)-2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-porphyrin-5-yl)-butyl]-cyclohexa-1,4-dienyl}-butyl)-[1,4]benzoquinone