C₄₆H₄₉F₁₇N₄O₁₀S₂

Base Information

• Chemical Name: C₄₆H₄₉F₁₇N₄O₁₀S₂
• CAS No.: 1643531-12-7
• Molecular Formula: C₄₆H₄₉F₁₇N₄O₁₀S₂
• Molecular Weight: 1205.02
• Mol file: 1643531-12-7.mol

Synonyms:C₄₆H₄₉F₁₇N₄O₁₀S₂

Chemical Property of C₄₆H₄₉F₁₇N₄O₁₀S₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₆H₄₉F₁₇N₄O₁₀S₂

There total 5 articles about C₄₆H₄₉F₁₇N₄O₁₀S₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

2BrH*C10H25N3O3S + C36H26F17NO8S (1643531-06-9) → C46H49F17N4O10S2 (1643531-12-7)

Guidance literature:

C₃₆H₂₆F₁₇NO₈S; With O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 20 ℃; for 1h;

2BrH*C₁₀H₂₅N₃O₃S; With sodium hydrogencarbonate; In N,N-dimethyl-formamide; for 16h; Cooling with ice;

DOI:10.1039/c4ob00456f

Reference yield:

C24H19NO5 (1307863-96-2) → C46H49F17N4O10S2 (1643531-12-7)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium carbonate / acetonitrile / 16 h / 20 °C

2.1: 2,6-di-tert-butyl-pyridine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate / 16 h / 155 °C / Sealed tube

3.1: hydrogenchloride / acetonitrile / 16 h / Reflux

4.1: O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 1 h / 20 °C

4.2: 16 h / Cooling with ice

With hydrogenchloride; 2,6-di-tert-butyl-pyridine; potassium carbonate; O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; In N,N-dimethyl-formamide; acetonitrile;

DOI:10.1039/c4ob00456f

Reference yield:

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl trifluoromethanesulfonate (171182-85-7) → C46H49F17N4O10S2 (1643531-12-7)

Guidance literature:

Multi-step reaction with 4 steps

1.1: potassium carbonate / acetonitrile / 16 h / 20 °C

2.1: 2,6-di-tert-butyl-pyridine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate / 16 h / 155 °C / Sealed tube

3.1: hydrogenchloride / acetonitrile / 16 h / Reflux

4.1: O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 1 h / 20 °C

4.2: 16 h / Cooling with ice

With hydrogenchloride; 2,6-di-tert-butyl-pyridine; potassium carbonate; O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; In N,N-dimethyl-formamide; acetonitrile;

DOI:10.1039/c4ob00456f

upstream raw materials:

C₃₆H₂₆F₁₇NO₈S

C₂₄H₁₉NO₅

3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl trifluoromethanesulfonate

C₃₄H₂₂F₁₇NO₅