ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Base Information

Chemical Name:ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate
CAS No.:949908-51-4
Molecular Formula:C₁₁H₁₆N₄O₄
Molecular Weight:268.272
Hs Code.:

Synonyms:ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Suppliers and Price of ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Chemical Property:

Purity/Quality:: 95%+ or 98%+ ^*data from raw suppliers

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Technology Process of ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

There total 13 articles about ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1196490-68-2
ethyl (3aR,4R,6S,7R,7aS)-7-(acetylamino)-6-azido-2,2-dimethylhexahydro-1,3-benzodioxole-4-carboxylate

: 949908-51-4
ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃;
DOI:10.1002/anie.200901345

Reference yield: 70.0%

: ethyl (3S,4R,5S)-4-acetamido-5-azido-3-hydroxy-1-cyclohexene-1-carboxylate

: 949908-51-4
ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Guidance literature:: ethyl (3S,4R,5S)-4-acetamido-5-azido-3-hydroxy-1-cyclohexene-1-carboxylate; With pyridine; trifluoromethylsulfonic anhydride; In dichloromethane; at -15 - -10 ℃; for 2h;

With potassium nitrite; 18-crown-6 ether; In N,N-dimethyl-formamide; at 40 ℃; for 24h;

Reference yield:

: C₁₀H₁₂N₄O₄

: 108-24-7
acetic anhydride

: 949908-51-4
ethyl (3R,4R,5S)-4-(acetylamino)-5-azido-3-hydroxycyclohex-1-ene-1-carboxylate

Guidance literature:: C₁₀H₁₂N₄O₄; acetic anhydride; With dmap; triethylamine; In acetonitrile; at 70 ℃; for 24h;

With methanol; sodium methylate; at 20 ℃; for 0.5h;