Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)

Base Information

• Chemical Name: Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)
• CAS No.: 1191408-26-0
• Molecular Formula: C₂₉H₁₈N₄O₆Ru
• Molecular Weight: 619.555

Synonyms:Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)

Chemical Property of Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)

Chemical Property:

Purity/Quality:

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Technology Process of Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine)

There total 2 articles about Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Ru(III)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine-4'-(4-phenylcarboxylate)) (1415722-09-6) → Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine) (1191408-26-0)

Guidance literature:

With (C₅Me₅)2Fe; In acetonitrile; monitoring by UV-spetroscopy;

DOI:10.1021/ja902942g

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 4'-(4-carboxyphenyl)-2,2':6',2-terpyridine sodium salt (1161783-92-1) + sodium dipicolinate → Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine) (1191408-26-0)

Guidance literature:

In not given; elem. anal.;

DOI:10.1021/ja902942g

Reference yield:

tetra-n-butylammonium hydroxide + Ru(II)(pyridine-2,6-dicarboxylate)(4'-(4-carboxyphenyl)-2,2':6',2''-terpyridine) (1191408-26-0) → (n-Bu4N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))] (1191408-28-2)

Guidance literature:

In N,N-dimethyl-formamide; elem. anal.;

DOI:10.1021/ja902942g

upstream raw materials:

Ru(III)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine-4'-(4-phenylcarboxylate))

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

4'-(4-carboxyphenyl)-2,2':6',2-terpyridine sodium salt

Downstream raw materials:

(n-Bu₄N)[Ru(II)(pyridine-2,6-dicarboxylate)(2,2':6',2''-terpyridine4'-(4-phenylcarboxylate))]

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