(1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

Base Information

Chemical Name:(1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde
CAS No.:136962-61-3
Molecular Formula:C₁₁H₁₇NO₃
Molecular Weight:211.261
Hs Code.:

Synonyms:(1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

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Chemical Property of (1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

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Technology Process of (1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

There total 2 articles about (1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 78-85-3,25120-30-3
2-methylpropenal

: 142891-87-0
(E)-1,3-butadien-1-yl N,N-dimethylcarbamate

: 136962-61-3
(1R,2S)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

: 136962-61-3
(1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

Guidance literature:: With (R)-BINOL-derived titanium complex 1a (X=Cl); 4 A molecular sieve; In dichloromethane; at 0 ℃; for 58h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0957-4166(00)86118-2

Reference yield:

: 78-85-3,25120-30-3
2-methylpropenal

: 142891-87-0
(E)-1,3-butadien-1-yl N,N-dimethylcarbamate

: 136962-61-3
(1R,2S)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

: 136962-61-3
(1S,2R)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

Guidance literature:: With (R)-BINOL-derived titanium complex 1a (X=Cl); 4 A molecular sieve; In dichloromethane; at 0 ℃; for 58h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0957-4166(00)86118-2

Reference yield:

: 136962-61-3
(1R,2S)-2-<(N,N-dimethylcarbamoyl)oxy>-1-methyl-3-cyclohexenecarbaldehyde

: (1R,2R)-2-(hydroxymethyl)-2-methylcyclohexanol

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether / 2 h / Ambient temperature

2: H₂ / 5percent Pd/C / ethanol / Ambient temperature

With lithium aluminium tetrahydride; hydrogen; palladium on activated charcoal; In diethyl ether; ethanol;
DOI:10.1021/ja00086a014