methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Base Information

Chemical Name:methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside
CAS No.:793692-26-9
Molecular Formula:C₂₁H₂₈INO₇
Molecular Weight:533.36
Hs Code.:

Synonyms:methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Suppliers and Price of methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

There total 3 articles about methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 41518-22-3
3-iodopropionyl chloride

: 793692-18-9
methyl 6-azido-4-O-cinnamoyl-6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside

: 793692-26-9
methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: methyl 6-azido-4-O-cinnamoyl-6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside; With triphenylphosphine; In diethyl ether; at 20 ℃; for 4h;

With hydrogenchloride; In diethyl ether;

3-iodopropionyl chloride; With sodium carbonate; In acetone; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2004.08.039

Reference yield:

: 140-10-3
(E)-3-phenylacrylic acid

: 793692-26-9
methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 85 percent / N,N'-dicyclohexylcarbodiimide; 4-(N,N-dimethylamino)pyridine / CH₂Cl₂ / 12 h / 20 °C

2.1: PPh₃ / diethyl ether / 4 h / 20 °C

2.2: aq. HCl / diethyl ether

2.3: 71 percent / aq. Na₂CO₃ / acetone / 1 h / 20 °C

With dmap; dicyclohexyl-carbodiimide; triphenylphosphine; In diethyl ether; dichloromethane;
DOI:10.1016/j.tet.2004.08.039

Reference yield:

: 147314-49-6
methyl 6-azido-6-deoxy-2,3-di-O-methyl-α-D-glucopyranoside

: 793692-26-9
methyl 4-O-cinnamoyl-6-deoxy-6-(3-iodopropanoylamino)-2,3-di-O-methyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1.1: 85 percent / N,N'-dicyclohexylcarbodiimide; 4-(N,N-dimethylamino)pyridine / CH₂Cl₂ / 12 h / 20 °C

2.1: PPh₃ / diethyl ether / 4 h / 20 °C

2.2: aq. HCl / diethyl ether

2.3: 71 percent / aq. Na₂CO₃ / acetone / 1 h / 20 °C

With dmap; dicyclohexyl-carbodiimide; triphenylphosphine; In diethyl ether; dichloromethane;
DOI:10.1016/j.tet.2004.08.039