(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

Base Information

Chemical Name:(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
CAS No.:1384985-12-9
Molecular Formula:C₁₈H₂₉O₄PSi
Molecular Weight:368.485
Hs Code.:

Synonyms:(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

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Chemical Property of (Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

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Technology Process of (Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

There total 1 articles about (Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 4090-55-5
2-chloro-5,5-dimethyl[1,3,2]dioxaphosphinane 2-oxide

: C₁₃H₂₀OSi

: 1384985-12-9
(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

Guidance literature:: C₁₃H₂₀OSi; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; at -78 ℃; for 0.75h; Inert atmosphere;

2-chloro-5,5-dimethyl[1,3,2]dioxaphosphinane 2-oxide; In tetrahydrofuran; at -78 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1055/s-0031-1290818

Reference yield:

: 1384985-12-9
(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

: 67753-90-6
9-phenethyl-9-bora-bicyclo[3.3.1]nonane

: 1384985-15-2
(E)-benzyldimethyl(1-phenylhex-4-en-3-yl)silane

Guidance literature:: With potassium tert-butylate; copper (I) acetate; In tetrahydrofuran; at 60 ℃; for 6h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1055/s-0031-1290818

Reference yield:

: C₁₆H₂₉BO₂

: 1384985-12-9
(Z)-2-{[4-(benzyldimethylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

: (E)-[9-(1,3-dioxan-2-yl)non-2-en-4-yl](benzyl)dimethylsilane

Guidance literature:: With potassium tert-butylate; copper (I) acetate; In tetrahydrofuran; at 60 ℃; for 6h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1055/s-0031-1290818