S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

Base Information

Chemical Name:S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate
CAS No.:1453814-05-5
Molecular Formula:C₃₂H₄₃NO₅S
Molecular Weight:553.763
Hs Code.:

Synonyms:S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

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Chemical Property of S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

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Technology Process of S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

There total 8 articles about S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 612-25-9
2-Nitrobenzyl alcohol

: 1453813-98-3
S-(12-(4-(3-hydroxy-3-methylbut-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

: 1453814-05-5
S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

Guidance literature:: With copper(ll) bromide; In nitromethane; at 20 ℃; for 12h; Darkness;
DOI:10.1016/j.tetlet.2013.07.144

Reference yield:

: 173349-34-3
tioacetic acid S-(12-bromododecyl) ester

: 1453814-05-5
S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate / N,N-dimethyl-formamide / 16 h / 90 °C

2: copper(ll) bromide / nitromethane / 12 h / 20 °C / Darkness

With potassium carbonate; copper(ll) bromide; In nitromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2013.07.144

Reference yield:

: 36603-49-3
4-(tetrahydropyran-2'-yloxy)-1-bromobenzene

: 1453814-05-5
S-(12-(4-(3-methyl-3-((2-nitrobenzyl)oxy)but-1-yn-1-yl)phenoxy)dodecyl) ethanethioate

Guidance literature:: Multi-step reaction with 4 steps

1: triethylamine; copper(l) iodide; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride / tetrahydrofuran / 12 h / 80 °C / Inert atmosphere

2: toluene-4-sulfonic acid / tetrahydrofuran; methanol / 4 h / 20 °C

3: potassium carbonate / N,N-dimethyl-formamide / 16 h / 90 °C

4: copper(ll) bromide / nitromethane / 12 h / 20 °C / Darkness

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; potassium carbonate; toluene-4-sulfonic acid; triethylamine; triphenylphosphine; copper(ll) bromide; In tetrahydrofuran; methanol; nitromethane; N,N-dimethyl-formamide; 1: |Sonogashira Cross-Coupling;
DOI:10.1016/j.tetlet.2013.07.144