[Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

Base Information

• Chemical Name: [Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)
• CAS No.: 208589-78-0
• Molecular Formula: C₁₀H₁₉N₂OPd*C₃₂H₁₂BF₂₄
• Molecular Weight: 1152.91

Synonyms:[Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

Chemical Property of [Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

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Technology Process of [Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

There total 1 articles about [Pd(CH₃)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(CH3CO)Pd(CO)(CH3)2CHNCHCHNCH(CH3)2(1+)*B[C6H3(CF3)2]4(1-)=CH3COPd(CO)(CH3)2CHNCHCHNCH(CH3)2B[C6H3(CF3)2]4 (208589-76-8) → [Pd(CH3)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)](1+)[B(3,5-(CF3)2C6H3)4](1-) (208589-78-0)

Guidance literature:

With nitrogen; In dichloromethane; byproducts: CO; (N2); bubbling N2 at -15°C for 10 min through a soln. of palladium complex in CH2Cl2; filtration through Celite, evapn. at -15°C, dissolving in CH2Cl2,pptn., washing with hexane at -15°C; elem. anal.;

DOI:10.1021/om000971n

Reference yield: 100.0%

1-ethenyl-4-methylbenzene (622-97-9,24936-41-2) + [Pd(CH3)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)](1+)[B(3,5-(CF3)2C6H3)4](1-) (208589-78-0) → CH3C6H4CHCH2COCH3Pd(CH3)2CHNCHCHNCH(CH3)2(1+)*B[C6H3(CF3)2]4(1-)=CH3C6H4CHCH2COCH3Pd(CH3)2CHNCHCHNCH(CH3)2B[C6H3(CF3)2]4 (208589-81-5)

Guidance literature:

In chloroform-d1; addn. of p-methylstyrene to complex soln. at -10°C, gentle heating to 20°C;

DOI:10.1039/a801158c

Reference yield: 94.0%

1-Phenylprop-1-yne (673-32-5) + [Pd(CH3)(carbonyl)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)](1+)[B(3,5-(CF3)2C6H3)4](1-) (208589-78-0) → [Pd(C(phenyl)=C(CH3)C(O)CH3)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)](1+)[B(3,5-(CF3)2C6H3)4](1-) (606081-30-5)

Guidance literature:

In dichloromethane; under N2; the alkyne added at -50 °C to CH2Cl2 soln. of the Pd complex; react. mixt. warmed at 0 °C within 2 h; after filtration through Celite, solvent evapd.; resulting solid washed with hexane; elem. anal.;

DOI:10.1021/om030368f

upstream raw materials:

(CH₃CO)Pd(CO)(CH₃)2CHNCHCHNCH(CH₃)2⁽¹⁺⁾*B[C₆H₃(CF₃)2]4^(1-)=CH₃COPd(CO)(CH₃)2CHNCHCHNCH(CH₃)2B[C₆H₃(CF₃)2]4

Downstream raw materials:

CH₃C₆H₄CHCH₂COCH₃Pd(CH₃)2CHNCHCHNCH(CH₃)2⁽¹⁺⁾*B[C₆H₃(CF₃)2]4^(1-)=CH₃C₆H₄CHCH₂COCH₃Pd(CH₃)2CHNCHCHNCH(CH₃)2B[C₆H₃(CF₃)2]4

[Pd(C(CH₃)=C(CH₃)C(O)CH₃)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

[Pd(C(phenyl)=C(CH₃)C(O)CH₃)(1,4-diisopropyl-1,4-diaza-1,3-butadiene)]⁽¹⁺⁾[B(3,5-(CF₃)2C₆H₃)4]^(1-)

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