Technology Process of 5-hexenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside
There total 5 articles about 5-hexenyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
trifluoromethanesulfonyloxy(triphenylphosphine)gold(I);
In
dichloromethane;
at 40 ℃;
for 0.333333h;
Overall yield = 73 %; Overall yield = 27 mg;
Inert atmosphere;
Schlenk technique;
Flow reactor;
DOI:10.1021/acs.orglett.5b01584
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 100 percent / 30percent HBr in AcOH / CH2Cl2 / Ambient temperature
2: Ag2CO3 / 4A molecular sieves / CH2Cl2 / 60 h / Ambient temperature
3: K2CO3 / methanol / 4.5 h / Ambient temperature
4: NaH / dimethylformamide / 8 h / Ambient temperature
With
hydrogen bromide; sodium hydride; potassium carbonate; silver carbonate;
4 A molecular sieve;
In
methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(96)00349-3
- Guidance literature:
-
Multi-step reaction with 3 steps
1: Ag2CO3 / 4A molecular sieves / CH2Cl2 / 60 h / Ambient temperature
2: K2CO3 / methanol / 4.5 h / Ambient temperature
3: NaH / dimethylformamide / 8 h / Ambient temperature
With
sodium hydride; potassium carbonate; silver carbonate;
4 A molecular sieve;
In
methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(96)00349-3
