C₅₄H₄₅BF₂N₆O₆S₆

Base Information

• Chemical Name: C₅₄H₄₅BF₂N₆O₆S₆
• CAS No.: 1542150-50-4
• Molecular Formula: C₅₄H₄₅BF₂N₆O₆S₆
• Molecular Weight: 1115.19
• Mol file: 1542150-50-4.mol

Synonyms:C₅₄H₄₅BF₂N₆O₆S₆

Chemical Property of C₅₄H₄₅BF₂N₆O₆S₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₄H₄₅BF₂N₆O₆S₆

There total 6 articles about C₅₄H₄₅BF₂N₆O₆S₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,7-dibromo-5,5-difluoro-10-(p-tolyl)-5H-4λ4,5λ4-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinine (1219941-27-1) + C22H26N2O3S3Sn (1542146-29-1) → C54H45BF2N6O6S6 (1542150-50-4)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tris-(o-tolyl)phosphine; In toluene; at 110 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c4nj00294f

Reference yield:

(5-(2-(2-methoxyethoxy)ethoxy)thiophen-2-yl)trimethyltin (1403231-21-9) → C54H45BF2N6O6S6 (1542150-50-4)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 24 h / Inert atmosphere; Schlenk technique; Reflux

2: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 12 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

3: tris-(o-tolyl)phosphine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene / 3 h / 110 °C / Inert atmosphere; Schlenk technique

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; diisopropylamine; tris-(o-tolyl)phosphine; In tetrahydrofuran; hexane; toluene; 1: |Stille Cross Coupling / 3: |Stille Cross Coupling;

DOI:10.1039/c4nj00294f

Reference yield:

4-bromo-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (501434-74-8) → C54H45BF2N6O6S6 (1542150-50-4)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 24 h / Inert atmosphere; Schlenk technique; Reflux

2: diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 12 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

3: tris-(o-tolyl)phosphine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / toluene / 3 h / 110 °C / Inert atmosphere; Schlenk technique

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; diisopropylamine; tris-(o-tolyl)phosphine; In tetrahydrofuran; hexane; toluene; 1: |Stille Cross Coupling / 3: |Stille Cross Coupling;

DOI:10.1039/c4nj00294f

upstream raw materials:

4-bromo-7-(thiophen-2-yl)benzo[c][1,2,5]thiadiazole

(5-(2-(2-methoxyethoxy)ethoxy)thiophen-2-yl)trimethyltin

3,7-dibromo-5,5-difluoro-10-(p-tolyl)-5H-4λ⁴,5λ⁴-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinine

C₂₂H₂₆N₂O₃S₃Sn