(pentamethylcyclopentadienyl)titanium tribenzyl

Base Information

• Chemical Name: (pentamethylcyclopentadienyl)titanium tribenzyl
• CAS No.: 107333-50-6
• Molecular Formula: C₃₁H₃₆Ti
• Molecular Weight: 456.507
• Mol file: 107333-50-6.mol

Synonyms:(pentamethylcyclopentadienyl)titanium tribenzyl

Chemical Property of (pentamethylcyclopentadienyl)titanium tribenzyl

Chemical Property:

Purity/Quality:

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Technology Process of (pentamethylcyclopentadienyl)titanium tribenzyl

There total 1 articles about (pentamethylcyclopentadienyl)titanium tribenzyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cp*TiCl3 (12129-06-5) + benzylmagnesium chloride (6921-34-2) → (pentamethylcyclopentadienyl)titanium tribenzyl (107333-50-6)

Guidance literature:

In not given; reaction was carried out in Et2O or hexane; product was isolated;

DOI:10.1039/c39860001118

Reference yield: 95.0%

(pentamethylcyclopentadienyl)titanium tribenzyl (107333-50-6) → {{C5(CH3)5}Ti(CH2C6H5)(O)}3

Guidance literature:

With H₂O; In acetonitrile; hydrolysis of Ti-compd. (acetonitrile) at 0°C under rigorous exclusion of air and moisture (O2-free Ar); allowing react. mixt. to warm to room temp., stirring (3 h), collecting ppt. by filtration and drying in vac.; 93% purity (NMR);

Reference yield:

(pentamethylcyclopentadienyl)titanium tribenzyl (107333-50-6) + t-butylnitrite (917-95-3) → Cp*Ti(Bz)2(ONBz(tBu))

Guidance literature:

In benzene-d6;

DOI:10.1039/b418778d

upstream raw materials:

Cp*TiCl₃

benzylmagnesium chloride