(+/-)-1,2-Propylene-d6 Oxide

Base Information

• Chemical Name: (+/-)-1,2-Propylene-d6 Oxide
• CAS No.: 202468-69-7
• Molecular Formula: C₃H₆O
• Molecular Weight: 64.0324
• European Community (EC) Number: 686-079-8
• DSSTox Substance ID: DTXSID40583741
• Nikkaji Number: J1.538.183C
• Mol file: 202468-69-7.mol

Synonyms:202468-69-7;(+/-)-1,2-Propylene-d6 Oxide;1,2-PROPYLENE OXIDE-D6;2,2,3-trideuterio-3-(trideuteriomethyl)oxirane;1,2-Epoxypropane-d6;Oxirane-d3,methyl-d3-(9ci);2-(?H?)methyl(?H?)oxirane;DTXSID40583741;2-(~2~H_3_)Methyl(~2~H_3_)oxirane;D97888;(+/-)-1,2-Propylene-d6 Oxide (Stabilized with hydroquinone);Propylene oxide-d6, >=98 atom % D, >=99% (CP), contains hydroquinone as stabilizer

Chemical Property of (+/-)-1,2-Propylene-d6 Oxide

Chemical Property:

• Melting Point: -112 °C(lit.)
• Refractive Index: n20/D 1.365(lit.)
• Boiling Point: 32.9 °C at 760 mmHg
• Flash Point: <-30 °F
• PSA: 12.53000
• Density: 0.997 g/cm³
• LogP: 0.40510
• Storage Temp.: 0-6°C
• XLogP3: 0
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 64.079525286
• Heavy Atom Count: 4
• Complexity: 26.5

Purity/Quality:

99% ^*data from raw suppliers

(+/-)-1,2-Propylene-d6Oxide(Stabilizedwithhydroquinone) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+,T
• Hazard Codes: F+,T
• Statements: 45-12-20/21/22-36/37/38-46
• Safety Statements: 53-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1CO1
• Isomeric SMILES: [2H]C1(C(O1)([2H])C([2H])([2H])[2H])[2H]
• Uses: 1,2-EPOXYPROPANE-D6 is a labelled Propylene Oxide, used in the synthesis of polyethylene glycol for use in plastics manufacturing.

Technology Process of (+/-)-1,2-Propylene-d6 Oxide

There total 1 articles about (+/-)-1,2-Propylene-d6 Oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.5%

d6-propylene oxide (202468-69-7) → (S)-2-(methyl-d3)oxirane-2,3,3-d3 (202468-69-7)

Guidance literature:

With (1S,2S)-(+)-[1,2-cyclohexanediamino-N,N’-bis-(3,5-di-tert-butylsalicylidene)]cobalt(II); acetic acid; In water-d2; toluene; at 0 - 20 ℃;

Reference yield: 41.4%

d6-propylene oxide (202468-69-7) → 1-aminopropan-1,1,2,3,3,3-d6-2-ol (1219795-13-7)

Guidance literature:

With ammonium hydroxide; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/d0cp03503c

Reference yield: 34.5%

d6-propylene oxide (202468-69-7) → (S)-2-(methyl-d3)oxirane-2,3,3-d3 (202468-69-7)

Guidance literature:

With (1S,2S)-(+)-[1,2-cyclohexanediamino-N,N’-bis-(3,5-di-tert-butylsalicylidene)]cobalt(II); acetic acid; In water-d2; toluene; at 0 - 20 ℃;

Downstream raw materials:

1-aminopropan-1,1,2,3,3,3-d₆-2-ol