methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

Base Information

Chemical Name:methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate
CAS No.:339307-09-4
Molecular Formula:C₂₅H₂₈N₂O₅
Molecular Weight:436.508
Hs Code.:

Synonyms:methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

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Chemical Property of methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

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Technology Process of methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

There total 6 articles about methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 339307-04-9
methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

: 339307-09-4
methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

Guidance literature:: With montmorillonite clay impregnated with copper(II) nitrate; acetic anhydride; In tetrachloromethane; at 20 ℃; for 0.5h;
DOI:10.1016/S0040-4020(00)01158-3

Reference yield:

: 1235-74-1,1757-97-7,2756-34-5,7151-00-0,10178-27-5,10178-29-7,21699-55-8,24035-60-7
Methyl dehydroabietate

: 339307-09-4
methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

Guidance literature:: Multi-step reaction with 5 steps

1: AlCl₃ / toluene / 4.5 h / 20 °C

2: 51 percent / montmorillonite clay impregnated with copper(II) nitrate; Ac₂O / CCl₄ / 20 °C

3: 96 percent / H₂ / Pd/C / ethanol / 20 °C

4: 87 percent / N,N-diisopropylethylamine / diethyl ether

5: 96 percent / montmorillonite clay impregnated with copper(II) nitrate; Ac₂O / CCl₄ / 0.5 h / 20 °C

With aluminium trichloride; montmorillonite clay impregnated with copper(II) nitrate; hydrogen; acetic anhydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrachloromethane; diethyl ether; ethanol; toluene;
DOI:10.1016/S0040-4020(00)01158-3

Reference yield:

: 1686-43-7
methyl (1R,4aR,10aR)-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene-1-carboxylate

: 339307-09-4
methyl (1R,4aR,10aR)-6-benzamido-1,4a-dimethyl-7-nitro-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 51 percent / montmorillonite clay impregnated with copper(II) nitrate; Ac₂O / CCl₄ / 20 °C

2: 96 percent / H₂ / Pd/C / ethanol / 20 °C

3: 87 percent / N,N-diisopropylethylamine / diethyl ether

4: 96 percent / montmorillonite clay impregnated with copper(II) nitrate; Ac₂O / CCl₄ / 0.5 h / 20 °C

With montmorillonite clay impregnated with copper(II) nitrate; hydrogen; acetic anhydride; N-ethyl-N,N-diisopropylamine; palladium on activated charcoal; In tetrachloromethane; diethyl ether; ethanol;
DOI:10.1016/S0040-4020(00)01158-3