(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

Base Information

Chemical Name:(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene
CAS No.:209251-06-9
Molecular Formula:C₂₄H₃₄O₂Si
Molecular Weight:382.618
Hs Code.:

Synonyms:(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

Suppliers and Price of (2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

Chemical Property:

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Technology Process of (2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

There total 1 articles about (2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35998-93-7
tri-n-butylcrotyltin

: 91751-24-5,92817-88-4,123284-89-9,112897-04-8
(R)-3-[(tert-butyldiphenylsilyl)oxy]-2-methylpropanal

: 209251-05-8
(2R,3R,4S)-1-((tert-butyldiphenylsilyl)oxy)-2,4-dimethylhex-5-en-3-ol

: 209251-06-9
(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

Guidance literature:: With borane-THF; 2,6-dimethoxybenzoyltartaric acid; trifluoroacetic anhydride; at -78 - -10 ℃; Product distribution;
DOI:10.1021/jo980145c

Reference yield:

: 209251-06-9
(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

: 209250-94-2
(2S,3R,4R)-5-(tert-Butyl-diphenyl-silanyloxy)-3-hydroxy-2,4-dimethyl-pentanal

Guidance literature:: With pyridine; dimethylsulfide; ozone; In methanol; dichloromethane; at -78 - 23 ℃;
DOI:10.1021/jo0267908

Reference yield:

: 209251-06-9
(2R,3S,4R)-1-(tert-butyldiphenylsilanyloxy)-2,4-dimethyl-3-hydroxy-5-hexene

: (2R,3R,4S,5S)-1-[(tert-butyldiphenylsilyl)oxy]-2,4-dimethyl-3,5,6-hexanetriol

: 209251-20-7
(2R,3R,4S,5R)-1-[(tert-butyldiphenylsilyl)oxy]-2,4-dimethyl-3,5,6-hexanetriol

Guidance literature:: With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In tetrahydrofuran; water; tert-butyl alcohol; at 23 ℃; Title compound not separated from byproducts.;
DOI:10.1021/jo0267908