cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene)

Base Information

• Chemical Name: cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene)
• CAS No.: 85412-97-1
• Molecular Formula: BF₄*C₃₁H₂₉AsNiP
• Molecular Weight: 652.961
• Mol file: 85412-97-1.mol

Synonyms:cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene)

Chemical Property of cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene)

There total 1 articles about cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(η-cyclopentadienyl)(η-cyclopentadiene)nickel tetrafluoroborate (84651-76-3) + 1-diphenylarsino-2-diphenylphosphinoethane (23582-06-1) → cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene) (85412-97-1) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8)

Guidance literature:

In chloroform; under Ar, Ni complex and ligand stirred in CHCl3 for 5 min; filtered, filtrate dropped in ether, filtered, dried in vac., elem. anal.;

DOI:10.1016/S0022-328X(00)98561-9

Reference yield:

cyclopentadienylnickel(diphenylphosphino(diphenylarsino)ethylidene) (85412-97-1) → [(C5H5)Ni((C6H5)2PCH2As(C6H5)2)CN]

Guidance literature:

With KCN; In water; benzene; under Ar, benzene soln. of Ni complex mixed with KCN in water, stirred for 10 min; org. phase separated, water phase extractd. with benzene, combined org.phases dried over Na2SO4, evapd. in vac. to dryness, residue washed with hexane;

DOI:10.1016/S0022-328X(00)98561-9

upstream raw materials:

(η-cyclopentadienyl)(η-cyclopentadiene)nickel tetrafluoroborate

1-diphenylarsino-2-diphenylphosphinoethane

Refernces