3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal

Base Information

• Chemical Name: 3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal
• CAS No.: 141462-75-1
• Molecular Formula: C₉H₁₄O₃
• Molecular Weight: 170.208
• Mol file: 141462-75-1.mol

Synonyms:3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal

Chemical Property of 3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal

Chemical Property:

Purity/Quality:

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Technology Process of 3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal

There total 1 articles about 3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

methyl 3,3-ethylendioxy-1-cyclohexenecarboxylate (141462-74-0) → (3-hydroxymethyl-1-cyclohexenyloxy)ethanol (142259-70-9) + 3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal (141462-75-1)

Guidance literature:

With lithium aluminium tetrahydride; In benzene; at 70 - 75 ℃; for 20h;

Reference yield: 65.0%

3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal (141462-75-1) → 3-(hydroxymethyl)cyclohex-2-en-1-one (76320-22-4)

Guidance literature:

With pyridinium p-toluenesulfonate; acetone; for 3.5h; Heating;

Reference yield:

3-hydroxymethyl-2-cyclohexen-1-one ethylen ketal (141462-75-1) → 3-(vinyloxymethyl)-2-cyclohexene-1-one (121056-74-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 65 percent / pyridinium tosylate, wet acetone / 3.5 h / Heating

2: 73 percent / Hg(OAc)2 / 18 h / Heating

With mercury(II) diacetate; pyridinium p-toluenesulfonate; acetone;

upstream raw materials:

methyl 3,3-ethylendioxy-1-cyclohexenecarboxylate

Downstream raw materials:

3-(hydroxymethyl)cyclohex-2-en-1-one

3-(vinyloxymethyl)-2-cyclohexene-1-one