trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

Base Information

Chemical Name:trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6
CAS No.:1084810-63-8
Molecular Formula:C₄₆H₄₀N₃O₃P₂Ru*F₆P
Molecular Weight:990.824
Hs Code.:

Synonyms:trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

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Chemical Property of trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

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Technology Process of trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

There total 1 articles about trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 2,6-diacetylpyridine dioxime

: ammonium hexafluorophosphate

: 157072-60-1,61521-25-3,166941-05-5,16971-33-8
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

: 1084810-63-8
trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

Guidance literature:: In methanol; to soln. of diacetylpyridinedioxime in MeOH ruthenium complex was added,refluxed for 14 h, filtered, concd., satd. soln. of NH4PF6 in MeOH was added; slowly evapd. at room temp., filtered, washed with MeOH, Et2O, dried in vac., elem. anal.;
DOI:10.1021/ic8009699

Reference yield: 70.0%

: 1084810-63-8
trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

: 1084810-94-5
trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]

Guidance literature:: With NaBH₄; In methanol; diethylene glycol dimethyl ether; ruthenium complex was stirred with NaBH4 (in giglime) in MeOH for 15 min; precipitate was filtered through sintered crucible, washed with MeCN, Et2O, dried in vac., elem. anal.;
DOI:10.1021/ic8009699

Reference yield: 66.0%

: 1084810-63-8
trans-[(κ3-diacetylpyridinedioxime)Ru(CO)(PPh3)2]PF6

: 1084811-03-9
trans-[(κ3-diacetylpyridinedioxime-NH)Ru(CO)(PPh3)2]PF6

Guidance literature:: With SOCl₂; In tetrahydrofuran; acetone; THF was added to soln. on ruthenium complex in acetone, concd. in water bath, cooled to room temp., filtered, SOCl2 was added to filtrate, stired for 2 h; evapd., vigorously boiled with water for several hours, filtered, washedwith Et2O, elem. anal.;
DOI:10.1021/ic8009699