endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

Base Information

Chemical Name:endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane
CAS No.:82521-83-3
Molecular Formula:C₂₆H₃₀O
Molecular Weight:358.524
Hs Code.:

endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0<sup>2,4</sup>>octane

Synonyms:endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

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Technology Process of endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

There total 9 articles about endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 82521-80-0
endo-2-formyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

: 19493-09-5
Methylenetriphenylphosphorane

: 82521-83-3
endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

Guidance literature:: In diethyl ether; for 60h; Heating;
DOI:10.1021/jo00140a026

Reference yield:

: 82521-66-2
2-bromo-anti-7-tert-butoxynorbornene

: 82521-83-3
endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

Guidance literature:: Multi-step reaction with 8 steps

1: 86 percent / copper(I) cyanide / dimethylformamide / 11 h / Heating

2: 45 percent / potassium hydroxide / H₂O / 24 h / Heating

3: 1.) 25percent aq. sodium hydroxide / 1.) HMPA, 25 deg C, 2 h, 2.) HMPA, 25 deg C, 6 h

4: 70 percent / hydroquinone / petroleum ether; diethyl ether / Ambient temperature; 2-3 weeks

5: 86 percent / toluene / Heating

6: 96 percent / lithium aluminum hydride / diethyl ether / 10 h / 25 °C

7: 89 percent / pyridinium chlorochromate / CH₂Cl₂

8: 70 percent / diethyl ether / 60 h / Heating

With potassium hydroxide; sodium hydroxide; lithium aluminium tetrahydride; copper(l) cyanide; hydroquinone; pyridinium chlorochromate; In diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; toluene; Petroleum ether;
DOI:10.1021/jo00140a026

Reference yield:

: 82521-67-3
2-cyano-anti-7-tert-butoxynorbornene

: 82521-83-3
endo-2-vinyl-exo-3,3-diphenyl-anti-8-tert-butoxytricyclo<3.2.1.0^2,4>octane

Guidance literature:: Multi-step reaction with 7 steps

1: 45 percent / potassium hydroxide / H₂O / 24 h / Heating

2: 1.) 25percent aq. sodium hydroxide / 1.) HMPA, 25 deg C, 2 h, 2.) HMPA, 25 deg C, 6 h

3: 70 percent / hydroquinone / petroleum ether; diethyl ether / Ambient temperature; 2-3 weeks

4: 86 percent / toluene / Heating

5: 96 percent / lithium aluminum hydride / diethyl ether / 10 h / 25 °C

6: 89 percent / pyridinium chlorochromate / CH₂Cl₂

7: 70 percent / diethyl ether / 60 h / Heating

With potassium hydroxide; sodium hydroxide; lithium aluminium tetrahydride; hydroquinone; pyridinium chlorochromate; In diethyl ether; dichloromethane; water; toluene; Petroleum ether;
DOI:10.1021/jo00140a026