dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

Base Information

Chemical Name:dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate
CAS No.:942621-49-0
Molecular Formula:C₂₆H₃₁O₆P
Molecular Weight:470.502
Hs Code.:

Synonyms:dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

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Chemical Property of dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

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Technology Process of dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

There total 4 articles about dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: dimethyl (8-hydroxy-3,7-dimethylocta-2,6-dienyl)phosphonate

: 579-18-0
3-benzoylbenzoic acid

: 942621-49-0
dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 20h;
DOI:10.1021/jo0623033

Reference yield:

: dimethyl geranylphosphonate

: 942621-49-0
dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

Guidance literature:: Multi-step reaction with 2 steps

1: 78 percent Turnov_. / tert-butyl hydroperoxide; SeO₂; salicylic acid / CH₂Cl₂ / 21 h / 20 °C

2: 82 percent / N,N'-dicyclohexylcarbodiimide; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 h / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; dicyclohexyl-carbodiimide; salicylic acid; In dichloromethane;
DOI:10.1021/jo0623033

Reference yield:

: 6138-90-5
trans-geranyl bromide

: 942621-49-0
dimethyl (E,E)-[8-(3-benzoylbenzoyloxy)-3,7-dimethylocta-2,6-dienyl]phosphonate

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / 4 h / Heating

2: 78 percent Turnov_. / tert-butyl hydroperoxide; SeO₂; salicylic acid / CH₂Cl₂ / 21 h / 20 °C

3: 82 percent / N,N'-dicyclohexylcarbodiimide; 4-(dimethylamino)pyridine / CH₂Cl₂ / 20 h / 20 °C

With tert.-butylhydroperoxide; dmap; selenium(IV) oxide; dicyclohexyl-carbodiimide; salicylic acid; In dichloromethane; 1: Arbuzov reaction;
DOI:10.1021/jo0623033