Lanthanum isopropoxide

Base Information

• Chemical Name: Lanthanum isopropoxide
• CAS No.: 19446-52-7
• Molecular Formula: C9H21LaO3
• Molecular Weight: 316.17
• Hs Code.: 29310099
• European Community (EC) Number: 625-147-3
• Nikkaji Number: J670.829C
• Mol file: 19446-52-7.mol

Synonyms:LANTHANUM ISOPROPOXIDE;19446-52-7;Lanthanum(III) isopropoxide;lanthanum(3+);propan-2-olate;lanthanum triisopropoxide;SORGMJIXNUWMMR-UHFFFAOYSA-N;AKOS025294821;FT-0746652;L0174

Chemical Property of Lanthanum isopropoxide

Chemical Property:

• Appearance/Colour: Off-white to pale yellow powder
• Melting Point: 120-128 °C
• Boiling Point: 170°C/0.04mmHg
• PSA: 27.69000
• Density: 170 °C/0.04mmHg
• LogP: 2.62710
• Storage Temp.: Flammables area
• Sensitive.: Moisture Sensitive
• Solubility.: Soluble in terahydrofuran, toluene, hexane and isopropyl alcohol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 316.055432
• Heavy Atom Count: 13
• Complexity: 10.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Lanthanum isopropoxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26-37/39

MSDS Files:

Useful:

• Chemical Classes: Metals -> Rare Earth Metals
• Canonical SMILES: CC(C)[O-].CC(C)[O-].CC(C)[O-].[La+3]
• Uses: Lanthanum(III) isopropoxide finds application in asymmetric catalysis. It forms complex with an (S,S)-phenyl-linked-binaphthol ,which enhances a catalytic 1,4-addition of malonate to cyclic and acyclic enones. It acts as a co-catalyst with copper fluoride-triphenylphosphine in catalytic allylation of ketoimines. Complex with an (S,S)-phenyl-linked-binaphthol which promotes a catalytic 1,4-addition of malonate to cyclic and acyclic enones. Co-catalyst with CuF-triphenylphosphine in a general catalytic allylation of ketoimines.