(+)-isoepijuvabiol

Base Information

Chemical Name:(+)-isoepijuvabiol
CAS No.:80373-62-2
Molecular Formula:C₁₆H₂₈O₃
Molecular Weight:268.397
Hs Code.:

Synonyms:(+)-isoepijuvabiol

Suppliers and Price of (+)-isoepijuvabiol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (+)-isoepijuvabiol

Chemical Property:

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Technology Process of (+)-isoepijuvabiol

There total 28 articles about (+)-isoepijuvabiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 80373-81-5
(R)-4-[(1S,3R)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-cyclohex-1-enecarboxylic acid methyl ester

: 80373-62-2
(+)-isoepijuvabiol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; for 7h; Heating;
DOI:10.1021/jo00339a054

Reference yield: 48.0%

: 145353-92-0
methyl (1'R,4R)-4-(2'-formyl-1'-methylethyl)cyclohex-1-ene-1-carboxylate

: 926-62-5
isobutylmagnesium bromide

: 58493-52-0,60134-56-7,60497-70-3,64314-14-3,76549-67-2,80373-62-2
methyl (4R,1'R,3'RS)-(+)-4-(1',5'-dimethyl-3'-hydroxyhexyl)-1-cyclohexenecarboxylate

Guidance literature:: In tetrahydrofuran; at -45 ℃; for 3h;

Reference yield:

: tert-Butyl-[(1R,3S)-1-isobutyl-3-((R)-6-methyl-7-oxa-bicyclo[4.1.0]hept-3-yl)-butoxy]-diphenyl-silane

: 80373-62-2
(+)-isoepijuvabiol

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent / diethylaluminum 2,2,6,6-tetramethylpiperidide / benzene / 3 h / 0 °C

2: 30 percent / lithium diethylamide / diethyl ether

3: 65 percent / PBr₃ / tetrahydrofuran / 0 °C

4: 88 percent / 2-nitropropane, KOH / H₂O; tetrahydrofuran; propan-2-ol / 1 h / 40 - 50 °C

5: 87 percent / manganese dioxide / acetic acid / 12 h / 22 °C

6: 88 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 7 h / Heating

With manganese(IV) oxide; potassium hydroxide; diethyl(2,2,6,6-tetramethylpiperidino)aluminium; 2-nitropropane; lithium diethylamide; tetrabutyl ammonium fluoride; phosphorus tribromide; In tetrahydrofuran; diethyl ether; water; acetic acid; isopropyl alcohol; benzene;
DOI:10.1021/jo00339a054