Triphenylmethylium tetrakis(perfluorophenyl)borate

Base Information

• Chemical Name: Triphenylmethylium tetrakis(perfluorophenyl)borate
• CAS No.: 136040-19-2
• Deprecated CAS: 152221-33-5,167776-69-4,1048008-82-7,1190226-63-1,1542157-45-8,2182687-34-7
• Molecular Formula: C43H15BF20
• Molecular Weight: 922.37
• Hs Code.: 29319000
• European Community (EC) Number: 685-485-2
• DSSTox Substance ID: DTXSID40888965
• Mol file: 136040-19-2.mol

Synonyms:(Ru(bpy)3)(B(C6F5)4)2;triphenylcarbenium tetra(perfluorophenyl)borate;triphenylmethylium tetrakis(2,3,4,5,6-pentafluorophenyl)borate;triphenylmethylium tetrakis(pentafluorophenyl)borate;triphenylmethylium tetrakis(perfluorophenyl)borate;tris(2,2'-bipyridyl)ruthenium(II) tetrakis(pentafluorophenyl)borate;trityl tetrakis(pentafluorophenyl)borate

Chemical Property of Triphenylmethylium tetrakis(perfluorophenyl)borate

Chemical Property:

• Appearance/Colour: Yellow to mustard colored powder
• Melting Point: 180-185℃
• PSA: 0.00000
• LogP: 10.55180
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility.: soluble in Methanol
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 7
• Exact Mass: 922.0947439
• Heavy Atom Count: 64
• Complexity: 1000

Purity/Quality:

99% ^*data from raw suppliers

Triphenylmethylium Tetrakis(pentafluorophenyl)borate >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 36/37/38-20/21/22
• Safety Statements: 36/37/39-26-22

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [B-](C1=C(C(=C(C(=C1F)F)F)F)F)(C2=C(C(=C(C(=C2F)F)F)F)F)(C3=C(C(=C(C(=C3F)F)F)F)F)C4=C(C(=C(C(=C4F)F)F)F)F.C1=CC=C(C=C1)[C+](C2=CC=CC=C2)C3=CC=CC=C3

Refernces

Tris(trimethylsilyl)sulfonium and Methylbis(trimethylsilyl)sulfonium Ions: Preparation, NMR Spectroscopy, and Theoretical Studies

10.1021/jo001248+

The research focuses on the preparation, NMR spectroscopy, and theoretical studies of tris(trimethylsilyl)sulfonium and methylbis(trimethylsilyl)sulfonium ions. These ions were prepared as long-lived species through reactions involving trimethylsilane, trityl tetrakis(pentafluorophenyl)borate (Ph3C+ TPFPB), and precursor sulfides such as hexamethyldisilathiane and methylthiotrimethylsilane. The resulting ions were characterized using 1H, 13C, and 29Si NMR spectroscopy at -78 °C. The study also attempted the synthesis of dimethyl(trimethylsilyl)sulfonium ion but was unsuccessful due to the formation of the more stable trimethylsulfonium ion. The structures and NMR chemical shifts of the ions were calculated using density functional theory (DFT) and IGLO methods, with results aligning well with experimental data.

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 136040-19-2 Trityl tetrakis(pentafluorophenyl)borate

Send

Send

Metric Ton KG G Pound L ML

Send

Send