[(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane

Base Information

• Chemical Name: [(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane
• CAS No.: 417701-42-9
• Molecular Formula: C₂₈H₃₃BiF₃NO₂S
• Molecular Weight: 713.617
• Mol file: 417701-42-9.mol

Synonyms:[(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane

Chemical Property of [(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane

Chemical Property:

Purity/Quality:

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Technology Process of [(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane

There total 1 articles about [(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Trifluoromethanesulfonamide (421-85-2) + tris(2,4,6-trimethylphenyl)bismuth dichloride (878499-76-4,181148-14-1) → [(trifluoromethanesulfonyl)imino]tris(2,4,6-trimethylphenyl)-λ5-bismuthane (417701-42-9)

Guidance literature:

With KO-t-Bu; In dichloromethane; KOtBu was added to mixt. of Bi-compound and ligand in CH2Cl2 at -50°C, warmed to room temp. with stirring under Ar; filtered, concd., under reduced pressure, crystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1021/ic0110575

upstream raw materials:

Trifluoromethanesulfonamide

tris(2,4,6-trimethylphenyl)bismuth dichloride