C₂₁H₃₂O₃SSi

Base Information

• Chemical Name: C₂₁H₃₂O₃SSi
• CAS No.: 1377313-83-1
• Molecular Formula: C₂₁H₃₂O₃SSi
• Molecular Weight: 392.635
• Mol file: 1377313-83-1.mol

Synonyms:C₂₁H₃₂O₃SSi

Chemical Property of C₂₁H₃₂O₃SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₁H₃₂O₃SSi

There total 2 articles about C₂₁H₃₂O₃SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C15H18O3S + t-butyldimethylsiyl triflate (69739-34-0) → C21H32O3SSi (1377313-83-1)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol301144a

Reference yield:

C12H12O3S (235793-15-4) → C21H32O3SSi (1377313-83-1)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; diethyl ether / 5 h / -78 °C / Inert atmosphere

2: triethylamine / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

With triethylamine; In tetrahydrofuran; diethyl ether; dichloromethane;

DOI:10.1021/ol301144a

Reference yield: 95.0%

C21H32O3SSi (1377313-83-1) → C21H34O4SSi (1377313-86-4)

Guidance literature:

C₂₁H₃₂O₃SSi; With 9-bora-bicyclo[3.3.1]nonane; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; at 0 ℃; for 5h; Inert atmosphere;

DOI:10.1021/ol301144a

upstream raw materials:

C₁₂H₁₂O₃S

t-butyldimethylsiyl triflate

Downstream raw materials:

C₂₁H₃₄O₄SSi

C₂₁H₃₄O₄SSi

C₂₁H₃₂O₄SSi

C₂₁H₃₂O₄SSi