Rh(OH)(ttp)

Base Information

• Chemical Name: Rh(OH)(ttp)
• CAS No.: 69069-21-2
• Molecular Formula: C₃₆H₃₈OP₃Rh
• Molecular Weight: 682.524
• Mol file: 69069-21-2.mol

Synonyms:Rh(OH)(ttp)

Chemical Property of Rh(OH)(ttp)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(OH)(ttp)

There total 2 articles about Rh(OH)(ttp) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.2%

hydroxy(1,5-cyclooctadiene)rhodium(I) dimer + Bis<3-(diphenylphosphino)propyl>phenylphosphin (34989-06-5) → Rh(OH)(ttp) (69069-21-2) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4)

Guidance literature:

In toluene; addn. of soln. of ttp to suspension of Rh-complex, stirring overnight ; all manipulations under inert atmosphere; evapn., addn. of hexane, collection of solid on Schlenk frit, washing with toluene (3 times) and hexane (four times), drying in vacuo, elem. anal.;

DOI:10.1021/om00105a013

Reference yield:

Rh(OC6H5)(ttp) (118657-58-2) → Rh(OH)(ttp) (69069-21-2)

Guidance literature:

With H₂O; In not given; under inert atmosphere;

DOI:10.1021/om00105a013

Reference yield: 78.0%

Rh(OH)(ttp) (69069-21-2) + benzoic acid (65-85-0,8013-63-6) → Rh(OC(O)C6H5)(ttp) (118657-64-0)

Guidance literature:

In benzene; addn. of soln. of benzoic acid to suspension of Rh-complex (formation of clear soln.), stirring for 1 h; all operations under inert atmosphere; evapn., addn. of hexane, pptn., collection of solid on a Schlenk frit, washing with hexane, drying in vacuo;

DOI:10.1021/om00105a013

upstream raw materials:

Rh(OC₆H₅)(ttp)

Bis<3-(diphenylphosphino)propyl>phenylphosphin

Downstream raw materials:

Rh(SO₂OH)(ttp).SO₂

Rh(OC(O)CF₃)(ttp)

Rh(OC(O)C₆H₅)(ttp)

Rh(OC(O)C₆H₄Br)(ttp)