benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

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Chemical Name:benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate
CAS No.:1419351-75-9
Molecular Formula:C₂₅H₂₃BrN₂O₂
Molecular Weight:463.374
Hs Code.:

Synonyms:benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

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Chemical Property of benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

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Technology Process of benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

There total 1 articles about benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 65899-49-2
1(E)-<(benzyloxycarbonyl)amino>-1,3-butadiene

: 20534-67-2,62618-44-4
N-benzylidene-3-bromoaniline

: 1419351-75-9
benzyl ((E)-2-((2S,4R)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

: 1419351-76-0
benzyl ((E)-2-((2S,4S)-7-bromo-2-phenyl-1,2,3,4-tetrahydroquinolin-4-yl)vinyl)carbamate

Guidance literature:: N-benzylidene-3-bromoaniline; With (R)-3,3'-di(anthracen-9-yl)-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diyl hydrogen phosphate; In toluene; for 0.0833333h; Schlenk technique; Molecular sieve; Inert atmosphere;

1(E)-<(benzyloxycarbonyl)amino>-1,3-butadiene; In toluene; at 20 ℃; for 16h; enantioselective reaction; Schlenk technique; Molecular sieve; Inert atmosphere;
DOI:10.1039/c2cc38002a