C₃₁H₄₃NO₈Si

Base Information

Chemical Name:C₃₁H₄₃NO₈Si
CAS No.:1265279-44-4
Molecular Formula:C₃₁H₄₃NO₈Si
Molecular Weight:585.77
Hs Code.:

C<sub>31</sub>H<sub>43</sub>NO<sub>8</sub>Si

Synonyms:C₃₁H₄₃NO₈Si

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Chemical Property of C₃₁H₄₃NO₈Si

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Technology Process of C₃₁H₄₃NO₈Si

There total 18 articles about C₃₁H₄₃NO₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1020070-44-3
2-(trimethylsilyl)-ethyl 3-amino-2,4-dihydroxybenzoate

: C₁₉H₂₆O₅

: 1265279-44-4
C₃₁H₄₃NO₈Si

Guidance literature:: With triethylamine; HATU; In N,N-dimethyl-formamide; at 23 ℃; for 14h; Inert atmosphere;
DOI:10.1002/ejoc.201001281

Reference yield:

: 1048970-79-1
C₂₉H₃₄O₃Si

: 1265279-44-4
C₃₁H₄₃NO₈Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

3.1: [bis(acetoxy)iodo]benzene; potassium hydrogencarbonate / 0.5 h / 0 - 23 °C / Inert atmosphere

4.1: Trimethyl borate / toluene / 16.3 h / 23 °C / Inert atmosphere; Reflux

5.1: palladium 10% on activated carbon; hydrogen / methanol / 0.5 h / 23 °C

6.1: pyridinium chlorochromate / dichloromethane / 16 h / 23 °C / Inert atmosphere; Molecular sieve

7.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 - 0 °C / Inert atmosphere

8.1: bis-triphenylphosphine-palladium(II) chloride; formic acid; tributyl-amine / N,N-dimethyl-formamide / 16 h / 23 - 78 °C / Inert atmosphere

9.1: sodium t-butanolate / diethyl ether / 2 h / 45 °C / Inert atmosphere

10.1: tert.-butylhydroperoxide / decane; ethyl acetate / 0.5 h / 23 °C / Inert atmosphere; Molecular sieve

10.2: 15 h / 23 °C / Inert atmosphere

11.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

11.2: 3 h / -78 - 0 °C / Inert atmosphere

12.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.58 h / -78 °C / Inert atmosphere

12.2: 4 h / -78 - 0 °C / Inert atmosphere

13.1: Hoveyda-Grubbs catalyst second generation / benzene / 1.17 h / 70 °C / Inert atmosphere

14.1: trimethylamine-N-oxide / tetrahydrofuran / 3 h / 23 - 70 °C / Inert atmosphere

15.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / water; tert-butyl alcohol / 1.5 h / 23 °C

16.1: triethylamine; HATU / N,N-dimethyl-formamide / 14 h / 23 °C / Inert atmosphere

With tert.-butylhydroperoxide; N,N,N,N,N,N-hexamethylphosphoric triamide; bis-triphenylphosphine-palladium(II) chloride; sodium chlorite; sodium dihydrogenphosphate; formic acid; Hoveyda-Grubbs catalyst second generation; 2-methyl-but-2-ene; Trimethyl borate; tributyl-amine; trimethylamine-N-oxide; [bis(acetoxy)iodo]benzene; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; potassium hexamethylsilazane; potassium hydrogencarbonate; triethylamine; HATU; pyridinium chlorochromate; sodium t-butanolate; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole; In tetrahydrofuran; methanol; diethyl ether; decane; dichloromethane; water; ethyl acetate; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; benzene; 1.1: Corey-Bakshi-Shibata reduction / 4.1: Intramolecular Diels-Alder reaction / 9.1: Wittig reaction;
DOI:10.1002/ejoc.201001281

Reference yield:

: 108534-61-8
(2-methoxyphenoxy)-(1,1-dimethylethyl)diphenylsilane

: 1265279-44-4
C₃₁H₄₃NO₈Si

Guidance literature:: Multi-step reaction with 17 steps

1.1: N,N,N,N,-tetramethylethylenediamine; sec.-butyllithium / diethyl ether; cyclohexane / 0.75 h / -78 °C / Inert atmosphere

1.2: 2 h / -78 °C / Inert atmosphere

2.1: (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole / tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

4.1: [bis(acetoxy)iodo]benzene; potassium hydrogencarbonate / 0.5 h / 0 - 23 °C / Inert atmosphere

5.1: Trimethyl borate / toluene / 16.3 h / 23 °C / Inert atmosphere; Reflux

6.1: palladium 10% on activated carbon; hydrogen / methanol / 0.5 h / 23 °C

7.1: pyridinium chlorochromate / dichloromethane / 16 h / 23 °C / Inert atmosphere; Molecular sieve

8.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 - 0 °C / Inert atmosphere

9.1: bis-triphenylphosphine-palladium(II) chloride; formic acid; tributyl-amine / N,N-dimethyl-formamide / 16 h / 23 - 78 °C / Inert atmosphere

10.1: sodium t-butanolate / diethyl ether / 2 h / 45 °C / Inert atmosphere

11.1: tert.-butylhydroperoxide / decane; ethyl acetate / 0.5 h / 23 °C / Inert atmosphere; Molecular sieve

11.2: 15 h / 23 °C / Inert atmosphere

12.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

12.2: 3 h / -78 - 0 °C / Inert atmosphere

13.1: N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane / tetrahydrofuran; toluene / 0.58 h / -78 °C / Inert atmosphere

13.2: 4 h / -78 - 0 °C / Inert atmosphere

14.1: Hoveyda-Grubbs catalyst second generation / benzene / 1.17 h / 70 °C / Inert atmosphere

15.1: trimethylamine-N-oxide / tetrahydrofuran / 3 h / 23 - 70 °C / Inert atmosphere

16.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / water; tert-butyl alcohol / 1.5 h / 23 °C

17.1: triethylamine; HATU / N,N-dimethyl-formamide / 14 h / 23 °C / Inert atmosphere

With tert.-butylhydroperoxide; N,N,N,N,N,N-hexamethylphosphoric triamide; bis-triphenylphosphine-palladium(II) chloride; sodium chlorite; sodium dihydrogenphosphate; formic acid; Hoveyda-Grubbs catalyst second generation; 2-methyl-but-2-ene; Trimethyl borate; tributyl-amine; N,N,N,N,-tetramethylethylenediamine; trimethylamine-N-oxide; [bis(acetoxy)iodo]benzene; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; sec.-butyllithium; potassium hexamethylsilazane; potassium hydrogencarbonate; triethylamine; HATU; pyridinium chlorochromate; sodium t-butanolate; (S)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole; benzo[1,3,2]dioxaborole; In tetrahydrofuran; methanol; diethyl ether; decane; dichloromethane; cyclohexane; water; ethyl acetate; N,N-dimethyl-formamide; toluene; tert-butyl alcohol; benzene; 2.1: Corey-Bakshi-Shibata reduction / 5.1: Intramolecular Diels-Alder reaction / 10.1: Wittig reaction;
DOI:10.1002/ejoc.201001281