Cyclododecyl phenyl selenide

Base Information

• Chemical Name: Cyclododecyl phenyl selenide
• CAS No.: 42066-65-9
• Molecular Formula: C₁₈H₂₈Se
• Molecular Weight: 323.38
• Mol file: 42066-65-9.mol

Synonyms:Cyclododecyl phenyl selenide

Chemical Property of Cyclododecyl phenyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Cyclododecyl phenyl selenide

There total 4 articles about Cyclododecyl phenyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

cyclododecane (294-62-2) + phenylselenyl benzenesulfonate (60805-71-2) → Cyclododecyl phenyl selenide (42066-65-9)

Guidance literature:

With 1,10-Phenanthroline; copper(l) cyanide; N-(tert-butyl)-N-fluoro-3,5-bis(trifluoromethyl)benzenesulfonamide; In 1,2-dichloro-ethane; at 60 ℃; for 24h; Inert atmosphere; Glovebox; Sealed tube;

DOI:10.1021/jacs.1c05874

Reference yield: 78.0%

cyclododecane (294-62-2) + diphenyl diselenide (1666-13-3) → Cyclododecyl phenyl selenide (42066-65-9)

Guidance literature:

With di-tert-butyl peroxide; at 120 ℃; for 18h; Reagent/catalyst;

DOI:10.1007/s12039-015-0981-0

Reference yield: 23.0%

diphenyl diselenide (1666-13-3) + C24H33OP (1331914-25-0) → Cyclododecyl phenyl selenide (42066-65-9)

Guidance literature:

With indium; iodine; In dichloromethane; for 4h; Reflux; Inert atmosphere;

DOI:10.5012/bkcs.2011.32.6.1847

upstream raw materials:

diphenyl diselenide

C₂₄H₃₃OP

cyclododecane

phenylselenyl benzenesulfonate

Downstream raw materials:

cis-cyclododecene

(E)-Cyclododecen

1,2-epoxycyclododecane

Refernces

• 1、 Sahoo, Santosh K. "A comparative study of Cu(II)-assisted vs Cu(II)-free chalcogenation on benzyl and 2°/3°-cycloalkyl moieties". . p. 2151 - 2157. Retrieved 2016/01/12.
• 2、 Ngernmaneerat, Poonlarp,Munbunjong, Wanida,Chavasiri, Warinthorn,Jang, Doo Ok. "A mild and efficient method for preparing alkyl phenyl selenides from alkyl diphenyl phosphinites". experimental part. p. 1847 - 1848. Retrieved 2012/01/05.